Metal-Metal bonds and isolobal analogy

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  • Опубліковано 18 гру 2024
  • Formula to calculate metal metal bonds in clusters and brief discussion on isolobal analogy.

КОМЕНТАРІ • 153

  • @shabnamdan7898
    @shabnamdan7898 7 років тому

    Thank you for posting this video, this will be a great help. Your method of teaching is really great.

  • @swatisharma-nt7ws
    @swatisharma-nt7ws 7 років тому

    Thanks a lot buddy.... ice doing a good cause for d ones who can't go anywhere for coaching due to some circumstances.really thanks

  • @RAJPAL-gg2yu
    @RAJPAL-gg2yu 7 років тому

    thanks sir very useful sorry I started now preparing for June 2018 so now I started watch ur videos very usefull thanks alot😊😊😊

  • @christinemathew4116
    @christinemathew4116 7 років тому

    Awesome video Sir...it has so much cleared my concepts.

  • @sdeb3333
    @sdeb3333 4 роки тому +1

    In W2(OPh)6 the OPh group is bridging that is why it contributes 3 electrons..but how do we know that it is bridging from the formula?

  • @A_chem
    @A_chem 4 роки тому +1

    Super explained 🔥🔥 I wish I get a chance to study organic chemistry 🙄

  • @gowthammanoharan2640
    @gowthammanoharan2640 7 років тому

    (16:14) It is Inorganic chemistry by Catherine E.Housecraft sir

  • @nehapandey4539
    @nehapandey4539 7 років тому

    your all vedios are very helpful sir thankyou so much

    • @nehapandey4539
      @nehapandey4539 7 років тому

      sir can u tell me a proper plan to prepare for csir june 2018 exam

  • @Bittu_Chem
    @Bittu_Chem 6 років тому

    thank ypu so much sir. i am your regular video viewer.. it helps me lot. 😊👍👌💐

  • @goonjthevoiceinside7574
    @goonjthevoiceinside7574 6 років тому

    Sir....You r simply amazing...... And ur way of explanation is perfect....

  • @educationtheonlyweapon5897
    @educationtheonlyweapon5897 6 років тому

    Excellent sir 👍👍👍your way of explanation is amazing
    Tq 😊

  • @saldias7475
    @saldias7475 7 років тому

    Sir can u tell me how to know if a particular ligand is acting as a bridging ligand in cluster and how to find the no of bridging ligands

  • @yogeshmanitripathi8452
    @yogeshmanitripathi8452 7 років тому

    is there any video on sigmatropic pericyclic reactions

  • @shabnamdan7898
    @shabnamdan7898 6 років тому

    Sir When there are two transition metals in a cluster than for the value of n we should take contribution of both the metals ?

  • @bharathipendli4877
    @bharathipendli4877 7 років тому

    Is your videos and practicing questions are sufficient for preparing net?

  • @navyakalingapatnam8018
    @navyakalingapatnam8018 6 років тому

    sir,is there any video about chemical periodicity?

  • @debojyotimukherjee262
    @debojyotimukherjee262 7 років тому

    Sir you just fab...sir plz keep updating us.

  • @kakalidevi2497
    @kakalidevi2497 7 років тому

    Is there any shortcut method to calculate the no of bridging ligand in metal complex ? It will be very much helpful for me if you solve the question no 25 from December 16 part a.

    • @kakalidevi2497
      @kakalidevi2497 7 років тому

      Is there any provision to buy the vedio?

  • @sanjuktamishra7930
    @sanjuktamishra7930 7 років тому

    Sir how many electrons O2 and S2 contribute in neutral counting of metal clusters ?

  • @uddalokkar7124
    @uddalokkar7124 6 років тому +1

    Sir , how to find out B.O. in clusters like [ Re2Cl8] (2-) . It will be of great help Sir

  • @akshpreetkaur6932
    @akshpreetkaur6932 7 років тому

    sir same formula can be used for nitrido and carbido metal cluster??? but there is error by using this formula for nitrodo metal cluster

  • @priyankajalotra2300
    @priyankajalotra2300 7 років тому

    Sir I have asked you earlier to explain ionic strength.. How to calculate it.. We find it usually in the Csir net in some way or the other.

  • @astammandal8824
    @astammandal8824 7 років тому

    Sir ,can you explain
    me why the bridge chlorine atom contributes 3 electron?

  • @manjunath.haramagatti5962
    @manjunath.haramagatti5962 7 років тому

    How to calculate no.of bridge and non bridge carbonyl group in metal cluster?

  • @sk-ml6ox
    @sk-ml6ox 7 років тому

    sir, plz explain , how to calculate bridging co or ligand

  • @finazkhan9382
    @finazkhan9382 6 років тому

    Styx code? What is it for BnHn

  • @aasthasingh9784
    @aasthasingh9784 7 років тому

    Thanks sir.... Plz upload video on jahn teller distortion

  • @growpotential9016
    @growpotential9016 7 років тому

    Sir i like ur videos very much
    I have a question calculate no. Of metal metal bond and bridge ligand in complex Co3(CH)(CO)9 given complex follow 18e rule

  • @ankitaupadhyay3545
    @ankitaupadhyay3545 6 років тому

    what will be the structure of Mn(2-B3H8)(CO)4? NIDO, CLOSO OR ARCHNO?

  • @bharathipendli4877
    @bharathipendli4877 7 років тому

    What should I do for getting another 80 marks.

  • @sadhguru2358
    @sadhguru2358 6 років тому

    sir please tell how to calculate number of bridged carbonmonoxide ligands in metal carbonyl clusters

  • @SantoshYadav-oh6ff
    @SantoshYadav-oh6ff 7 років тому

    Sir will u pls make a vedio on association dissociations and interchange of inorganic mechanism

  • @anjushakurian8180
    @anjushakurian8180 6 років тому

    Sir pls make videos on all the important topics of csir.bcz, your lectures are really helpful for understanding of topics clearly

  • @Venki_Talks
    @Venki_Talks 5 років тому

    Can you please explain how to calculate Bond order in Nb6Cl12^2+

  • @sapnabarad2739
    @sapnabarad2739 7 років тому

    sir OR contribute 3 or 1 electron ,? i m little confused

  • @sagar07wagh
    @sagar07wagh 7 років тому

    Very nice good job sir

  • @prakashsaha1449
    @prakashsaha1449 5 років тому

    How can I calculate number of Terminal CO present in Fe2(CO)9 ?

  • @sakshimehta7787
    @sakshimehta7787 7 років тому

    sir can u please make a video on how much a ligand contribute and secondary in isolobal analogy can we a fragment which has 6 electrons

  • @sapnabarad2739
    @sapnabarad2739 7 років тому

    HELLO sir ...sir how many electron that OR contribute in Mo2(OR)6.. sir pls tell me

  • @jagatjotkaur4551
    @jagatjotkaur4551 7 років тому

    Sir,how to calculate bond order for (Re2cl8)2-, (Re2Cl6 (P(C2H5)3)2, and (Re2Cl4(P(C2H5)Ph2)4)

  • @chemistrywithsrinivassir8522
    @chemistrywithsrinivassir8522 7 років тому

    Excellent, thank you very much sir

  • @aasthaaggarwal348
    @aasthaaggarwal348 7 років тому

    Sir please tell how to calculate bond order in metal halide clusters eg in [Nb6Cl12] 2+

  • @navjottaluja1871
    @navjottaluja1871 6 років тому

    Hey sir.. will it be sufficient to watch inorganic and physical videos provided by you for june net?

  • @dixjain9635
    @dixjain9635 5 років тому

    Is H is isolobal to CH3???

  • @pgboy5149
    @pgboy5149 7 років тому

    sir ..I tried to calculate..bond order of Re2cl8^-2...the way u tought..it is coming out 6..bt it has M-M &bond order = 4...how sir?

    • @alkasharma4161
      @alkasharma4161 6 років тому

      Manish Tripathi because it is follow 16 electron if u take 16 electron in place of 18 electron then get 4

  • @sapnabarad2739
    @sapnabarad2739 7 років тому

    SIR howmany electron that HPO4 contribute in [MO2(HPO4)4]-2

  • @pragyamaheshwari7718
    @pragyamaheshwari7718 6 років тому

    Sir how to determine bridgeing ligands

  • @sachukc
    @sachukc 7 років тому

    sir how can we find the coordination number of phosphorus in compound (PMo12O40)3-??
    I mean compound -(phosphorus molybdenum 12 0xygen40)3- can you help me sir?

  • @ruchiipant3089
    @ruchiipant3089 7 років тому

    Thanku Sir...ur videos are awesome...Very helpful...Can you explain difference between isoelectronic and isolobal analogy...???

  • @nargisjafriofficial
    @nargisjafriofficial 7 років тому

    Very nice explanation but can u give a list which will tell us the valence electrons different ligands carry...since organic students find difficulty in knowing the no.of electrons ligands carry like in this example OPh ligand

    • @nargisjafriofficial
      @nargisjafriofficial 7 років тому

      Ok...thank you

    • @chetnahasija9975
      @chetnahasija9975 7 років тому +2

      Nargis Parvaneh there is a pdf file available online.just type 18 e rule pdf you'll find a list of ligands there.Hope it helps

    • @nargisjafriofficial
      @nargisjafriofficial 7 років тому

      BK Chetna HASIJA Oh thank you so much

  • @sautrickchowdhury89
    @sautrickchowdhury89 7 років тому

    very nice explanation...guess you were talking about Inorganic Chemistry by CATHERINE E. HOUSECROFT AND ALAN G. SHARPE

  • @kitymaurya3102
    @kitymaurya3102 7 років тому

    Sir plz provide the electrons contributed by the ligands commonly asked in CSIR NET .....

  • @ishikajha9355
    @ishikajha9355 7 років тому

    thanks.it is really helpful.sir plz upload video on orgel diagram nd tanabe sugano diagram.

  • @priyankagupta6575
    @priyankagupta6575 7 років тому

    sir what is structure of Me2C2B10H10?

  • @nehasinghneha3974
    @nehasinghneha3974 7 років тому

    Thankuu. Nice lecture

  • @sunandinipaturi1332
    @sunandinipaturi1332 5 років тому

    Sir plzz calculate m-m bonds in [W2(oph)9]-3 and how can calculate when metal having a oxidation state .🙏🙏

  • @sivan9219
    @sivan9219 7 років тому

    Sir, good morning
    Am preparing like which of the complex obey 18 rule... In this question we can't remember the contribution of the ligands... And also in this video metal metal bond also need to know the contribution of ligands.. So pls suggest some important points it will help lot like me.. Thank you sir..

    • @sivan9219
      @sivan9219 7 років тому

      K sir.. Thank you

  • @shalukumari8280
    @shalukumari8280 6 років тому

    sir can u plz explain isopoly n heteropoly acids

  • @indrajitmahto5113
    @indrajitmahto5113 7 років тому

    You are from which place??

  • @sachukc
    @sachukc 7 років тому

    sir phosphorus nitrogen compounds and sulfur nitrogen compounds structures...can u give one class.it is well described in huheey .any other tricks to remember these structures..

  • @DrRKKadu
    @DrRKKadu 6 років тому

    Please solve M-M bond in Re2Cl8)-2 ??
    By applying ur Formula..
    I tried.. But m not getting correct ans

  • @sivaramakrishna4249
    @sivaramakrishna4249 6 років тому

    Sir,how many metal metal bonds in {Mo2(OAC)4},could you explain.

  • @RahulGupta-ki1wt
    @RahulGupta-ki1wt 7 років тому +2

    Sir how many electrons RS group contributes in isolobal analogy. Question number 138 June 2014 B series

    • @chembasicsbysujitkumar3705
      @chembasicsbysujitkumar3705 6 років тому

      actually it contributes 7 elctrons as = 1+6 = 7 elctrons and so it is isolobal with Mn(CO)5 = 7 + 10 = 17 electrons
      as both of them are deficient with 1 electron

  • @menkavishwakarma3449
    @menkavishwakarma3449 6 років тому

    Sir (Re(Cl)4(PMe2Ph) 4) + ma metal metal kitne hoga

  • @Utopia_of_Joy
    @Utopia_of_Joy 7 років тому

    Sir, I just want to clear a doubt.
    Isn't bond order means no. of bonds between metal and not total M-M bond in the cluster? So, in case of W2(OPh) 6 we use 30/2 =15 then 18-15=3 i. e. Bond order is 3 though there are only 2 W so both will give same answer.
    I am having doubts please correct me if I'm wrong.

  • @dhikshasharma8960
    @dhikshasharma8960 7 років тому

    Sir plzzzz answer the question of quantum of 2marks june 2017 .....it is 1d box in between 0,8 interval .....47 of series A ..plzzzzzzz it hardly takes 2 min

  • @vishalsukhija7393
    @vishalsukhija7393 7 років тому +3

    How OPh contribute 3e, it only contribute 3 if it is bridging nd if it is terminal den contribute only 1e.
    Am i ryt sir?

    • @jagadeeshmanda2497
      @jagadeeshmanda2497 7 років тому

      Vishal Sukhija yes sir plz clarifie doubt

    • @vishalsukhija7393
      @vishalsukhija7393 7 років тому

      jagadeesh manda any lone pair containing ligand present on bridging position with 2 metal always contribute 3e, if metal is three then it will contribute 5e

    • @jagadeeshmanda2497
      @jagadeeshmanda2497 7 років тому

      Vishal Sukhija yes sir i agree with u

    • @Samikshn24
      @Samikshn24 6 років тому

      Sir please clarify the doubt....OPh contributes 3 e- only while forming bridges

  • @sk-ml6ox
    @sk-ml6ox 7 років тому

    how can we know no. of bridging and non bridging co ligand

  • @dhikshasharma8960
    @dhikshasharma8960 7 років тому

    Sir plzzz upload a video on mno rule for deducing skeltal electrons......m not able to get thru it from book .....this is given in every book.......nd i hv an intuition dis tym mno rule will cm.....plz plz plz plz upload before sunday

  • @priyankagupta6575
    @priyankagupta6575 7 років тому

    Sir can you please a video on bio inorganic chemistry ?

  • @ParthFunJam
    @ParthFunJam 6 років тому

    Help me to solve the metal metal bond in [(C5H5)Fe(CO)2]2

  • @Nanocreator2023
    @Nanocreator2023 7 років тому

    Please explain Mo(OR)6 M-M Bonds

    • @Nanocreator2023
      @Nanocreator2023 7 років тому

      Gate chemistry I'm sorry, its Mo2(OR)6

    • @Nanocreator2023
      @Nanocreator2023 7 років тому

      Gate chemistry sir, please give the calculations.. m not able to get it right

  • @ChemistryTadkaSachinshukla
    @ChemistryTadkaSachinshukla 6 років тому

    (Re2cl8)²- how many matel matel bond

  • @radhikakp2613
    @radhikakp2613 6 років тому

    sir i want a topic for my project..

  • @sudheer2643
    @sudheer2643 7 років тому

    Sir plz provide some more csir shortcuts for bits

  • @brindhasubramanian7375
    @brindhasubramanian7375 6 років тому

    sir y we using 18 in formula

  • @WOA09
    @WOA09 6 років тому

    sir can u plz solve question no.124setA june2016

  • @reshmapatil6659
    @reshmapatil6659 5 років тому

    Sir ur videos are very helpful n u explain very well but I feel ur voice is not clear n can't see what u write on board so if can work it on ,, other wise excellent

  • @rahulbishnoi7948
    @rahulbishnoi7948 7 років тому

    sir plz give video for quantum chemistry

  • @sapnabarad2739
    @sapnabarad2739 7 років тому +2

    sir total M-M bond in Rh6(CO)16 ?

  • @habeebaunnisa9344
    @habeebaunnisa9344 7 років тому

    sir wi u please dicuss complete inorganic chemistry topics related to csir net

  • @priyankabansal9980
    @priyankabansal9980 7 років тому +5

    sir pls make a video on 18 electron rule as it has come almost in every gate nd csir queation papers

  • @X_plore
    @X_plore 7 років тому

    Sir please make a video on Quantum Chemistry, specifically for perturbation theory.

  • @devigag6647
    @devigag6647 6 років тому

    Tq so much sir... Sir plz tell me the valence electrons for some important ligands... I have my exam on tmrw sir... Replay me pls

  • @bobbalisandhya4861
    @bobbalisandhya4861 5 років тому

    Plz sir make a concise vedio on reactions of carbohydrates

  • @piyushpattanaik1829
    @piyushpattanaik1829 5 років тому

    then tell one simplifying the example of tungsten having 4 in no.s and tell the bond order related to no of metal-metal bond in the cluster.

  • @venkateshtakshak8336
    @venkateshtakshak8336 6 років тому +1

    I'm south indian student that's why sir don't mind I'm always follow ur topics only sir...

  • @thechemistsclub7471
    @thechemistsclub7471 4 роки тому

    Great sir #thechemistsclub

  • @chemistrylover2327
    @chemistrylover2327 7 років тому

    Sir please upload bio inorganic chemistry

  • @abdevilliers7112
    @abdevilliers7112 7 років тому +1

    Sir please make a video on How to find bridged, terminal ligands in given compounds

  • @bobbalisandhya4861
    @bobbalisandhya4861 5 років тому

    Gd evng sir please make a vedios on photo chemistry

  • @dixjain9635
    @dixjain9635 6 років тому

    It is applicable to only metallocarbonyl but what we do if we have another metal bond for example V2(O)12....

  • @incredibleminds3322
    @incredibleminds3322 7 років тому +2

    sir, please upload videos on inner and outer sphere mechanism

  • @nehathakur-yg8sf
    @nehathakur-yg8sf 5 років тому

    Thanks a lot sir

  • @nivasmane5747
    @nivasmane5747 6 років тому

    thank you sir

  • @Nrshimh
    @Nrshimh 7 років тому

    Thank u Sir...

  • @priyapriyu8435
    @priyapriyu8435 6 років тому

    Very nice

  • @aratrikasahana8252
    @aratrikasahana8252 7 років тому

    Thanks sir

  • @deeh9260
    @deeh9260 6 років тому

    Thankyou so much !

  • @priyankabansal9980
    @priyankabansal9980 7 років тому

    thankyou sir...!!!