Oxidation at the Benzylic Position with KMnO4 and MnO2

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  • Опубліковано 16 гру 2024

КОМЕНТАРІ • 18

  • @blonsh3072
    @blonsh3072 3 роки тому +4

    This finally makes sense, thank you! Also cutest ochem teacher ever

  • @safiaqureshi3939
    @safiaqureshi3939 2 роки тому +3

    Hey great video thank you for making it! I need to know the mechanism if you have any ideas?

  • @bic1349
    @bic1349 3 роки тому +1

    Fantastic demonstration!

  • @davidyadav2503
    @davidyadav2503 4 роки тому +3

    really good explanation

  • @laurenbling5705
    @laurenbling5705 8 місяців тому

    What happens when a linear alkene is reacted with H2SO4 and kmno4 where both carbon in double bond are tertiary?

  • @umiba18
    @umiba18 Рік тому

    Made it sound easy and fun!!! Thank you

    • @jOeCHEM
      @jOeCHEM  Рік тому

      Thank you so much for the kind words and for watching!

  • @zainabrizik5545
    @zainabrizik5545 4 роки тому +1

    great video! can you do benzylic ether cleavage and CrO3 oxidation? (from chapter 22 of the textbook)

  • @martinsikula5562
    @martinsikula5562 6 місяців тому

    How would a cyklohexylbutanal react with KMnO4?

  • @junkaccount2535
    @junkaccount2535 3 роки тому

    Hey Joe, how do we oxidize a specific substituent? Say there's a problem like the one you worked with a methyl and a 4-carbon chain at ortho, para positioning. My problem is I need to oxidize the methyl only and leave the 4-carbon substituent the same. Any ideas?

  • @YouMockMe
    @YouMockMe 3 роки тому +1

    Cool! Thanks for posting

  • @drrakeshkumar851
    @drrakeshkumar851 4 місяці тому

    What is the mechanism of the 1st reaction?

  • @rbc812
    @rbc812 3 місяці тому

    Why not directly use H+ in one single step instead of using OH- in the first step then followed by H+ in the second step?

  • @vanessaaitkensilva4279
    @vanessaaitkensilva4279 2 роки тому

    yeah but what about the mechanism????

    • @jOeCHEM
      @jOeCHEM  2 роки тому

      Hey, Vanessa! My content is geared toward what an undergraduate organic I and II course would cover, and this mechanism isn't something I've ever encountered being included in an undergraduate level course nor do I have any experience with it, so unfortunately, I can't help in regards to the mechanism :(
      Take a look at www.masterorganicchemistry.com/reaction-guide/oxidation-of-aromatic-alkanes-with-kmno4-to-give-carboxylic-acids/ (also mentioned here that the mechanism is very complicated and not well known) & check out the advanced resources linked on that page. Otherwise, if you HAVE to know this mechanism, I would ask your instructor for assistance if you're having issues with it. Thanks for watching, and again, sorry I couldn't' help with the mechanism.

  • @loopwholer
    @loopwholer 10 місяців тому +1

    give me the mechanism.. or else...

  • @willagibson6625
    @willagibson6625 Рік тому

    he is so me

  • @sundance8623
    @sundance8623 Рік тому

    What about the oxidation of a benzyl alcohol or benzyl chloride?......how for an aldehyde