E2 Stereochemistry With Newman Projections

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5:21 how do you know there's only 2 ways we can put these?

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I need the case in which the H and the Br are not already alligned and you have to rotate the bonds of 60° degrees.

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Single bonds are freely rotable means it doesnt matter whether it is 60,120 or 180 u can rotate them like the way you please

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[@biscuitstix_]

1:51 why is the CH3 on a stick and not a dash?

[@cameronpatel1457]

It’s because the carbon connected to the CH3 is no longer stereogenic and it becomes planar

[@biscuitstix_]

@ I just learned it today finally! I think it’s because the carbon becomes sp2, right?

[@cameronpatel1457]

@ that’s a reason because carbons that are bonded to an alkenes cannot be stereogenic so yes sp2, but if the carbon does not have 4 different group then it’s not stereogenic meaning no wedge or dash.

[@biscuitstix_]

@ okay so I’m not 100% sure I understand. is it just about its hybridization, or are there other factors? sorry if I seem kind of stupid, organic chem is difficult for me

[@cameronpatel1457]

@@biscuitstix_ it’s other factors too you have to make sure it’s a stereogenic center, but I have an exam tonight

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[@jacobnavarro7993]

does the E isomer always form with higher priority? (in the last example, for the conformation to be changed to E, the eclipsed newman projection would have to be used...is this eclipsed conformation more common in order to obtain E conformation? or does the staggered conformation take priority regardless of the less stable Z product?)

[@PunmasterSTP]

I think the cis/trans or E/Z isomerism has to deal with the orientation of the molecule in which the leaving group and the hydrogen (on the adjacent carbon atom) are trans to each other. AFAIK only one product would be produced, since E2 has to have this orientation to proceed.

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