Mixing sodium with mercury
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- Опубліковано 30 гру 2018
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Correction: at 12:50 I said that pure nitrogen is denser than air, but that isn't true. The specific gravity of nitrogen vs dry air at STP is ~0.97, meaning that it should rise slightly, but the difference (0.97 vs 1) is so small that there isn't a very noticeable effect. When air is flushed out of a flask by nitrogen, it would take a while, but it should eventually mix with the air out of the flask.
For this video, I'll be making the sodium amalgam, which is commonly used in chemical reactions. It can also be used as a gateway to other amalgams, even some that are normally very hard to form. This is the first official video in my new amalgam series, where I try and combine as many different metals as possible with mercury.
Related Videos:
• Aluminum and Mercury: • Aluminum and Mercury
• Dissolving Gold in Mercury: • Dissolving Gold in Mer...
• Sodium vapor lamp footage: • Grow Lights Explained:...
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Nile talks about lab safety: • Chemistry is dangerous.
Music in credits (Walker by SORRYSINES): / walker - Наука та технологія
science man mixes poison shiny water with boom water
- science book in big year
big if true
Much revelation
Based and redpilled
His new name is science man and all of his fan will now call him that
NileRed: "working with mercury is almost always a pain, requires waste management and special handling..."
Cody: "in this video we'll mix liquid mercury with Kool Aid and drink it!"
Danilo Pinheiro lol that’s Cody
That's Cody for ya.
Hahaha
@@scdhl1856 why the politics? Keep that shit out of here
I was thinking the same thing lol
"Why the hell would you want to mix explosives and poison?"
Me: *A M A L G A M A T I O N S*
DC and Marvel tried that once. We got Logan Wayne. Fun times.
Table salt: *....*
ua-cam.com/video/HUReu9ds2uE/v-deo.html
@@solierafromtheultrareconsquad Salty intensified.
I read that in Shadiversity's voice lol
Me: Cant afford much
Nile: ah yes, let me feed gold to my pet puddle
Nice one.
the gold was woth like 5 cents
@@GooseWithNoEggs i know, it was a joke stop ruining it
ua-cam.com/video/HUReu9ds2uE/v-deo.html
Ah it's 1 atom thick
"Bro just wash the sodium with water lol"
-Famous Last Words
Rip🙏
bruh just mix chlorine and muriatic acid for a stronger dissolver
@@Sir_Isaac_Newton_ Bain?
@@Sir_Isaac_Newton_ dontcha mean bleach and vinegar? :^)
@@ayrendraganas8686 I thought it was bleach and ammonia.
"There was a thump, and all the sodium instantly disappeared."
Sodium in a nutshell lol.
Nope, it reacts with nutshells too, there's no way you could keep it in one.
Isaac Roebuck lmao
sodium LOOKS LIKE CHEESE!
@@isaacroebuck9514 silence
@@isaacroebuck9514 Aren't you funny!
A poem about my father [who lived to 92, better living through chemistry]:
Willie was a chemist. Willie is no more,
For what he thought was H20 was H2S04.
Deam
Deam
Deam
@Hand Grabbing Fruits Funny.
@@AN-om1qc What does that mean?
I dont understand why people dislike videos like this. There is LITERALLY NOTHING to dislike.
They probably hold their phones upside down while watching.
Maybe it has something to do with something political he said at one point? Or maybe they don't like his voice. I dunno lol
Or they hate not understanding and feel insulted by not being a supergenius
Gets mercury poisoning.
"This is not ideal"
This is not okie dokie
This seems rather unfortunate...
The situation at hand is currently not the most desirable.
Move your ass!
An unfavorable outcome has arrived in which it does not meet the ideal nor is it sought after, which puts the situation at a disadvantage due to its lack of meeting an appropriate result.
This is the chemistry I always wanted to see. Weird UA-cam recommendation has finally something good!
😂😂😂 good one
Watch backyard scientist
It is not wierd!!!
It is Nile red 😍😍😍
I suggest you start with an english recommendation, first.
@@killerkirby366 or applied science or AvE or Cody’s lab
9:51 “but anyway, now that all that safety has talks done, i can go back to playing with the amalgam.” lol
ua-cam.com/video/HUReu9ds2uE/v-deo.html
Lol
I actually like chemistry unlike most of my family and I definitely LOVE this channel because it shows the extremely fun (and dangerous) aspects of chemistry
then you should watch explosions and fire al you need to know is in the name
One of the best high school chemistry teachers I know of:
"OK students, today we're going to the school pool. Why? Because there's an important lesson for us to learn there. We are not allowed, as teachers, to allow students to handle sodium, because it's very dangerous. We are also not allowed to put sodium into water in the classroom. Today, *WE ARE NOT IN THE CLASSROOM* because of this rule."
A year later:
"OK students, today we're going to the school pool. Why? Because there's an important lesson for us to learn there. We are not allowed, as teachers, to allow students to handle sodium, because it's very dangerous. We are also not allowed to put raw sodium into water under any circumstances. So instead, I am going to carefully lay out this sheet of paper so it's floating on the surface of the water. And now, I will drop this piece of sodium onto the paper. Remember, I'm not dropping the sodium into water, because that would be breaking the rules and rules are important to follow."
Best teacher ever
I wish I had this teacher
Mr.Lowe
Sodium speedboats! Always fun to play around with. That and the jelly baby cannon.
Can I have that teacher? :)
Years ago my roommate and I played around with a material we nicknamed "Hell Metal." Not a mercury amalgam but an alloy of gallium and aluminum. We dissolved powdered aluminum in molten gallium into no more would go in, then removed the aluminum oxides dross. Result is a liquid alloy that is relatively stable in dry air, wets glass, makes great mirrors of all your glassware, and if not disturbed may remain liquid at room temperature for anywhere from hours to weeks before it solidifies. It tears apart water on contact to produce hydrogen, evolving a fair amount of heat - learned that the hard way when I tried washing some off a gloved hand and received a burn for my trouble. Handy reductive agent.
I am totally gonna try this. I love youtubers that run their own experiments lol stay safe and never give up!
@@maximiliancollins1748 this sounds cool lol
@repentandbelieveinJesusChrist2 🍆🤡🎯
Imagine this in a water squirt gun, or pellet form while it is raining
Thanks that's really cool and interesting
20:01 "I'm sorry Mistress, I'm SURE I can fit all of them in my mouth"
LOLWUT? Is that someone's name?
I work with HID lighting and found this episode the answer to many of my questions. Great video!
“So to get things started, I added a few drops of acid.” Me, at every party
was searching for this
that's the rule
you drop cid at parties? i got big doubts
You need gallons of LSD
Actually lol
Imagine having science channels like this on UA-cam, and then showcasing “melting lipstick” as a science experiment representing all science channels.
And imagine that that was actually one of the better parts of the video. Oof UA-cam Rewind was bad
I'm still trying to figure out why everyone is talking about that stupid video. I never even knew UA-cam rewind was a think until electro boom did a video about it. Who cares? It's just a stupid video put out by UA-cam. K-pop!
@@xenonram Everyone is talking about it precisely because it's so stupid
What if they combined mercury and lipstick? 🤔
@@WG55 Kardasian
I think this is my favorite video that you've done. I really like these amalgamations.
This video deserves to be in the list of Really useful videos
"Smashing it a BIT" *destroys flask completely*
Happened with me soo many times it's not even funny.
Rhythm Jain same here.
Well, he started out very carefully...
@Matrix29bear < You mean pushing Sodium under Mercury with furry paws. lol
I've just gotta say that I have absolutely nothing to do with chemistry. I am not a chemistry student nor do I have anything to do with chemistry in my job, yet I really enjoy all of your videos as they are super interesting and extremely high quality. You are so good at making interesting and educational videos that you attract people that have barely anything to do with the matters you cover in your videos. I'll have to thank you for all your effort you put into your videos, it's really obvious that you value high quality content and take great effort to produce your videos! Cheers!
Great inspiration 👏
I get a light-hearted chuckle out of some of the comments but of course I do realize that like myself you're on novice and experimentation is how we learn. Many times by watching one another's experiments we learn not to do that other times we learn to take chances and other times to go forward for if it wasn't for the novice experimenter bathtub chemist a lot of what we have now wouldn't be possible.
@@tomking6926 Lets stop calling it chemistry though. The word has been hijacked
Love the behind the scenes look at your channel! Glad to see it’s so successful!!
Congratulations on your promotion! I'm proud of you. The new place looks excellent. Here's to growing out of this one too!
Nile, you fuel all of my nerd needs. I love your channel and recommend it to all.
Indeed.
With Cody's Lab and AvE in the mix my physics/enginerding nerdiness is fulfilled.
I used to dabble in Chemistry related experiments in my younger years (back in the 1970's). I remember ordering some sodium. It came crated in a wooden box filled with sand. The sodium was in an airtight can embedded in this sand. When I got done with my experiments I stored the unused portion of the sodium in a jar filled with kerosene such that the sodium was completely covered by the kerosene. Now the funny part is over time I noticed the remaining sodium was dwindling. In fact, every time I looked at the jar there was less and less sodium. Turns out my younger brother was "borrowing" some of my sodium every now and then to put on a little "fireworks show" for his friends. He would cut a piece of sodium and toss it into a puddle and watch the "fireworks" LOL.
P.S. I should add that the reason I stored the leftover sodium in kerosene was to keep it from reacting with water and oxygen in the atmosphere.
LOL That sounds so funny! That's so cool that you did that :)
Lmao
@@Someone-ig7we Yes, it was. I was cool about my brother using some of the sodium. Namely because I would have done the same damned thing...LOL
Funny lil story 😃👍
Good man!
Wow! You’re a diehard research chemist! As a former chemist I really enjoy these videos ! Best wishes for success in your endeavors !
another great video been watching you for a while love your content you're really good work I love how you've grown and love your knowledge it's amazing keep up the great work me and my children and my wife and my brothers love watching it
I would like to see NaK mixed with mercury, you just know that has to be fun.
I had that idea too! Like!
The reaction is violent, but similar to the sodium one. The nak splatters and boils. Can be done in argon.
1:22 "But first, let me show you some of my exotic cheese collection."
Forbidden cheddar
I really enjoyed your test, I like mercury.
Looking for to seeing your other videos.
Thank you for making them!
This is great chemistry and entertaining! Thank you.
0:14 "It's almost always a bit of a pain because it requires special handling"
*proceeds to mix it with another metal that requires special handling*
Exactly
Hg? Na...
Ha!
That’s great...
Nice
K.
He He He
Y'know, you've inspired me to want to become a chemistry teacher. Keep up all your great work.
Hopefully your dream becomes true!
Fantastic Channel, and amazing storytelling gifts you have. Keep up the great work! 👍
I can't believe I end up watching every one of his videos in their entirety when I couldn't stay awake in school courses I paid for haha
Intro to chem day 1 the professor mixed up this "liquid" that spent the entire class changing colors as it was stirred. I never missed his class... guess you have to lead with cool science to draw us in... it worked !!!
I know i am writing this 2 years late but please continue with this series of Mercury experiments, I see a huge potential for generating info by exploring an obscure area of chemistry. In order to get a pH.D don't you have to develop information that was previously unknown, it would be cool to see you get a doctorate in chem and document it online.
Just found your channel and it’s amazing bro!
So happy to brought back to your Channel!
I feel like you’re gonna get elemental fluorine at some point. Cody will probably be first though
Fluorine scares me
@@NileRed I think every chemistry based youtube channel says that.
@@NileRed flourine scares everyone!
Yes, Cody likes dangerous things.
it is even possible to make it without electricity, but it requires some nasty chemical intermediates
*reads title* sounds safe
I love how the sodium dissolved/boiled off in the water like an effervescent tablet reversing the initial reaction and restoring the mercury back to original liquid state 😃 awesome!
No idea how I got here but you have an interesting channel and I am curious about amalgams now. Job well done buddy !!! Thank You
It would be cool to see the crystals under a microscope.
"there was a thunk and the sodium disappeared"
Yea... That's kinda what sodium tends to do
Sodium: aight imma head out
Some reductions with sodium amalgam are actually done in dil. HCl. Alternatively, if too high or too low pH is to be avoided, boric acid can be used as a buffer.
I love this. We need this mercury series to keep going. It's super interesting.
If this keeps on going then Nilered won't be.
I'm watching this in late 2020 and all I can say is CONGRATS! Love the videos and keep doing them please! So interesting and I love trying to guess what happens and also wish I majored in this field. So interesting. Good format. Love it!
8:15
"I have absolutely no ideia what the concentration of sodium is here"
"but I think it's somewhere around 5%"
ok
ok
ok
ok
ok
I guess the advantage of an amalgam is the mercury working as a medium for electron transfer. This allows reductions that would be more difficult with just sodium and a proton source (e.g. sodium in ethanol).
Examples I know of include reduction of decalin to tetralin and of harmaline to leptaflorine.
You can measure the concentration of sodium by decomposing the amalgam in water, then titrating the liquid with acid until neutral:
2 NaHg + 2 H2O -> 2 NaOH + 2 Hg + 2 H2
NaOH + HCl -> NaCl
I want to say I really appreciate your channel. I'm still a high school student and I have yet to take a chemistry course, but your channel helps me understand so many different reactions. You explain things in a manner I can comprehend and I've learned so much. Thank you.
How was your chemistry class? 😃
"Mercury requires special handling, as well as waste management"
Codyslab: "haha, Mercury go brrrr"
No gloves
Mercury is very nasty but aluminium can be too, If it go to lungs.
I’ve no idea why this popped up in my feed, but I’m glad it did.
New sub here.
Made sodium amalgam many times when in graduate school for organic chemistry. The procedure I used was to melt the sodium by boiling in toluene, allow the toluene to evaporate and quickly add the mercury via an addition funnel. The resulting liquid was then quickly poured into a mortar and stirred with a pestal while it solidified. This would result in a course powder which could be easily stored and weighed when needed.
Really excited to see this series continue; I don't understand most of what you're saying but the amalgam at the end looked so cool
*NileRed hiring his brother*
Me: "Chemical Brothers"
Fullmetal alchemist live action
Request: Try an ultrasonic bath (jewelry cleaner) to mix the amalgam and keep it from solidifying. Possibly also breaking the surface tension so a glass rod is not needed. Also try with tuning forks (and a rubber butt to prevent breaking the glass on contact).
your videos are clear and engaging, and somehow you manage to pack actual chemistry into them
Somehow.... He literally does chemistry so I'm sure it's pretty easy for him
I love how informative you are about absolutely everything you talk about.
This channel always reminds me why I decided to pursue a chemistry major. I love watching your videos when I’m in need of motivation to actually study
1:23
The sodium metal looks like cheese-
*The forbidden cheddar*
Back in the early 80’s I worked in an aluminum foundry, and we used sodium to refine the eutectic silicon grain distribution. The sodium was encapsulated in small aluminum cans making it safe for storage. These would be preheated, then added and stirred into the molten aluminum. As years passed, the industry turned to Titanium boron as a much safer grain refinement option, and our inventory of sodium capsules was forgotten…by most😂.
I would take a handful of these on weekends down to the river, poke holes in the can, tie to a rock, then drop them into the 70-100 foot deep river. In the darkness, you would see flashes in the deep and a muffled rumble. A few seconds later the surface would boil up with bubbles and smoke, and tiny pieces of sodium would burn purple and pop about as they reacted.
Unfortunately, we didn’t have cell phones with video capability back then (and pretty sure I wouldn’t video that today).
On getting the percentage of sodium higher, my bet would be higher temperatures, either initially, or through adding more sodium leading to a longer positive feedback loop.
you dont want the positive feedback loop, what you want is low temperatures and a very deep chamber to mix in so that the sodium doesnt reach the surface
That ammonia reaction was the coolest thing I have ever seen! Keep up the awesome work!
I realized science is actually very fun when u understand everything. I just studied the chapter about s-block elements, and this whole reaction was there to prepare caustic soda (NaOH) so i understood everything word by word. This video reminded me why i took science lol.
0:46 boys in the morning:
agreed.
I don't know why but i feel sad every time you smash a glass tube.
You always say something like "i was hoping i could just pop it out, but i can't."
That always makes me feel like you're all disappointed. it always comes off as like, "I tried to save my near and dear glass tube. I truly did, but alas, my efforts were futile. I'm sorry, my glass tube, that it has to end in this way. But your contributions will not be forgotten. Your end will not be in vain. you will be a part of something much greater. Hundreds of thousands of people shall see your ultimate sacrifice to science," Mr.Science man says, tears building in his eyes.
And then you give the glass tube a slow death with a hammer, and it takes a few tries, like the glass tube is trying to resist. it just makes me feel like I've lost something. and I feel so silly every time it happens.
J_mac225 7:31
@@christianoconnor9031 thanks
Thanks im crying now.
@Audiocronic Please...no more
Glass Tube: Dad it hurts! Please stop! Dad.... I love you..
Can you do a video on making (synthesising I guess) ethanol? I know it's far far easier to ferment sugar but a chemical process would be fascinating.
....takes me back to my alcoholism days
Burn ethane
@@quickscience5090 That'll just produce water and CO2, like all other simple hydrocarbons. Some ethanol might be produced as an intermediary here and there, but that's highly unlikely, and if it were to happen, it'd immediately burn as well. And since it'd be only an intermediary, the reaction wouldn't constitute a synthesis.
The industrial method is to pass ethene and steam over a silicon dioxide and phosphoric acid catalyst. This has to be done multiple times, as only about 5% of the ethene is converted to ethanol in each pass. It has to be done at 300 deg C, and 60 to 70 atm pressure.
I love this video. I have been a huge fan of chemistry sine I was around 7-8 but never really got into it other than basic kid experiments.
This voice is for my time to bed, its realy relaxing
You should do a chemistry-off with Cody
Nilered would win. He's an actual chemist.
Nile would win. I like both of them, but cody's specialty is geology.
Maybe not a competition (as was said, NileRed seems to have more proper chemistry experience, whereas Cody just knows enough to use for practical purposes), but definitely a collaboration between the two would be interesting.
cody is doing physical chem while nile is doing synthetic chem. you cant really compare them
A colab is what they should do, would be awesome.
I like your videos as they are easy to understand and fun too, they help me a lot in my Chemistry, Thank You @NileRed.
The ammonia amalgam reaction looks vaguely like what you see of a screen from an MRI to be honest. Super damn cool!!
I hated chemistry in school always Im much more biology and zoology science minded but I always love these videos you break down everything as best as you can for simple people like me if you taught my chemistry class I would have loved chemistry haha
Hey Nile, huge fan of your work. One thing I'd like to suggest that I think would be cool is some slow motion of these reactions that you do. Especially with the Belousov-Zhabotinsky reaction. It would be neat to be able to see how these reactions originate and maybe have you break down each stage and discuss it. Just an idea. Keep it up, can't wait to see what else you come up with
I died when he dropped sodium after washing with toluene
So did he
This experiment looks so cool
I doubt this will get seen because older video but, coal contains a lot of impurities like mercury, I found some chunks of coal by railroad tracks went "oh neato" and kept them. Tossed them in my aluminum truck tool box and kinda forgot about it. Even in the coal and in small amounts it still damaged and started pitting the box. Kinda cool really, didn't do any serious damage but still awesome. And I only knew it was mercury in the coal thanks to awesome people like you and Cody's lab not trying to promote him but you both have expanded my knowledge on science and chemistry so thank you for that.
I love you’re videos.You really inspire me to pursue chemistry.Thanks Nile
anyone gonna press videos.you ?
I just did.Nothin’ appeared unfortunately
Moritz Schäfer now i want to make a site for that
The question is what kinda site we are gonna make?!
@@moritzschaferalthaus3461 the site sounds like something youll find on the dark web lmao
Making sodium amalgam is a lingering (half-day) work, it requires paying attention. The most important thing the inert atmoshere (do it under argon or nitrogen) Depending on the quantity but you have to use KPG stirrer. The second important step is to use freshly cut sodium (before washed the mineral oil with dry hexane or petrolether) and you have to cut the sodium to small slices and added to to the mercury in small portions. The mercury reacts so violently with the sodium that it boils locally. (after every slices you can hear a loud hissing) :)
Could you do a video on your chemistry journey? Would love to see it!!
Watching these videos is making me miss my junior high science class, our science teacher did some wild demonstrations with every highly reactive metal he could get his hands on
My favorite mercury reaction was the gold foil one. the way the mercury almost eats the gold leaf paper looks so cool!
is it possible to make sodium wool, like steel wool, so u have a ton of surface area. if u put this in water how violent would it be with the increased surface area
I'm sure you could, but you would have to draw it into very fine wire in an inert atmosphere so that the sodium wouldn't almost instantly react with the oxygen in the air.
Hell, make it out of caesium
There's no point to that when you could grind it to powder instead for an even larger surface area.
Sodium actually reacts with water fat faster in the form of solid lumps due to electrically driven mixing
@@theCodyReeder funny seeing you here. I've seen your comments on lots of science channels I watch. We must have similar scientific interests.
When you first cut that big piece of sodium, I thought, OMG. 🌋. Love your videos. Especially working with the Mercury . Schools in UK no longer use it for H&S reasons, which is pretty understandable.
Have you ever considered working with frequency?
Good luck my friend.👍🏻👏🏼
As much as I love your experiments one of the main things I use your channel for is to fall asleep lol no disrespect at all your commentary is just super relaxing lol
You use the long video playlist for sleep aid as well? His voice is super relaxing and it's always fun to guess which video you'll wake up to if you put the playlist on loop. 😌💙
An interesting video. Thanx for the upload, NileRed.
A couple of points - as mentioned by other commenters, nitrogen is slightly lighter than air, not heavier. But it's OK for creating an inert covering for your amalgam if you're quick enough at stoppering the container.
Mineral oil is not, of course, a solvent for sodium metal (if it were, your sodium would be in solution, wouldn't it!)
It should have come as no surprise to you that the article by Read and Lucarini on the large-scale preparation of sodium amalgam in the lab was an old paper - it says so at the bottom of the page! (Industrial & Engineering Chemistry, 1925, vol. 17, part 5, p. 480 [a one-page-only article] for those of you voyeurs who understand that there's more to chemistry than the miserly offerings we find on the internet).
Interesting and great news that you've found a kind landlord who's provided you with some premises to work in - they know about the nature of your experiments I take it?
You're not sure what use to make of your sodium amalgam? Ooooooh! Do you not have access to any alpha, beta-unsaturated carbonyl compounds (or similar)? Your amalgam should work a treat at reducing them. Also, try a reaction with an alcohol to make the corresponding sodium alcoholate as a strong base.
You may like to try making an amalgam with about 35-45% Na by weight; this should also be a liquid at round about room temperature or a little above. The (approx. 40%) eutectic melts at about 21 C.
Good luck, best wishes, and please do keep up the good work :)
I always watch through ads for nile's videos so he can do more chemistry
If I'm not mistaken this is a way to 'charge' the mercury. Old gold mines would use a copper plate, coated with 'charged' mercury on a shaker table to capture and amalgamate the fine gold from the oar being mined. Charged mercury is like a gold magnet
I love this series so much hey NileRed have you ever thought of doing like a chemistry tips and trick to help students learning chemistry to better understand the basics? #NileRed
NR: the rxn is very exothermic and can burst into flames
Also NR: *didn't submerge the flask in cold water bath*
Me: excuse me wtf
what if shock heating breaks the glass? this is not a danger in this example, but it could be a problem
Water + sodium = fire anyway?
Nilered: I like to live on the edge
When i first took chemistry as a prerequisite for my science degree these were the experiments i thought we would be doing. I could not have been anymore wrong. Chemistry was easily the worst science class i ever took. So much math and very little interesting experiments. However with that being said i really enjoy your channel because you take everything that captivated me about chemistry and make it interesting. I wish you were my teacher. I think what people don't understand or respect about this channel is just how much of an education you have to have in order to be able to safely perform these experiments correctly. You have to be far into a chemistry degree before ever being able to do this kinda of stuff lol. Ill stick to my biology courses lol.
Nile Red is an example for what we should all
Sub to:
Good Channel with the concept of rare-but-epic Uploads.
I mean, Tier Zoo, Oversimplified and Hbomberguy, they are all Top-Tier but dont
put any Strain on youre Time-Schedule, right?
Always love ur channel is really helpful
Whenever I’m bored, I watch these videos. I’m not an expert scientist so I don’t fully understand some things but find these videos really interesting and entertaining
Did you ever end up doing this series, I'm really interested in the amalgamation of different metals.
Dont know anything about this stuff but that was really cool!
I find it very interesting that it sticks to glass... Have a feeling it's gunna revolutionize production methods for displays sooner or later...