Metal Nitrosyls (Part-1) Bonding : Linear & Bent NO Groups

[@kishorkhadka7752]

Very good explanation. Thank you sir! Keep loading other videos as well

[@chemlogs]

thanks dear ......

[@taleemzone2276]

Well explained👏

[@realfacts9183]

MashaAllah.
Sir bht acha explain kya ap ne..

[@chemlogs]

Thanks for your feedback...keep watching , learning and sharing..

[@aleenaakram3207]

Concept clearing leacture🤩

[@afsheenkhan5471]

Best way of explanation...Great Sir

[@chemlogs]

Thanks

[@MotivatewithTripathi]

Sir main class 12th up board se hu mujhe video me jyada kuch to samjh nahi aaya par mera ek doubt hai ki NO nutral hai par sir mere chemistry wale teacher NO par(+1) charge consider karte hai to sir mujhe koi resion bta dijiye jise main proof kar saku ki NO nutral hai. Pls sir kafi time se ye question mere mind me hai aur aap meri aakhiri ummid ho 🙏🏻

[@chemlogs]

Actually when NO is in free state means not bonded to anything else (as a ligand) then its neutral....
However when NO is bonded to some metal atom as a ligand then it is either in the form of NO+ (mostly) or in the form of NO- (less common)...hope you understand this ..you are welcome to ask any further questions..

[@chemlogs]

The evidence for neutral NO came from IR spectroscopic Data in accordance with MOT...

[@MotivatewithTripathi]

@@chemlogs Thats very kind of you sir 🙏🏻
sir actually baat ye hai ki class 12 chemistry co-ordination compound chapter me iupac name likhna rahta hai to ek compound hai "K3[Fe (CN)5 NO].2H2O" to sir isme NO ko nutral consider karna hai par sir mere chemistry wale teacher is particular compound me NO par (+1) consider karte hai jiske wajah se oxidation number bhi galt aati hai to sir main unhe kaise proof karu ki is compound me NO nutral hai ❓🙏🏻

[@chemlogs]

NO ko neutral ligand hi consider kya jata hy simply ....so oxidation state is +2...
But when we go to details or higher level Actually NO is present as NO+.....or NO per + tab aata hy jab wo metal ko 1 electron transfer karta hy ...
Fe +2 + 1e =Fe+1
Fe +1 & NO+1 = +2
5 CN = -5
Net charge on complex anion in both cases is= -3
But for simplification we mention Fe (ii)
......

[@chemlogs]

Bonding of NO with metal is a bit complicated...
NO is a pi acceptor ligand ....
Firstly it gives one electron to metal and becomes NO + ...
Then it forms a coordinated covalent bond by donating/ sharing an electron pair with metal....
Finally metal donates one electron pair back to the NO through pi bonding ...since it accepts pi electron so it's called as pi acceptor ligand...
So it donates 3 electrons and accepts 2.. overall it gives 1 electron..That's why NO+

[@farhanaahmad408]

JazakAllah

[@abubakkarsaddeeq391]

Very effective , excellent explanation.. Thank u..

[@abubakkarsaddeeq391]

Sir I need PDF of these slide ...plzx

[@chemlogs]

Whatsapp me 03124009181

[@abubakkarsaddeeq391]

Ok sir

[@Maryam_Khalid_g6i]

Aysa q lgrha k ap khd se hi bat krrhe ha yha😮 apka nam b abu bakar ha

[@chudharyarooj6199]

Sir very help fulllll Thanks a Lot

[@chemlogs]

Welcome beta..

[@muhammadtayyab4738]

Nice sir

[@ranaarslan7572]

❣❣

[@maheshbs-p-0176]

Sir yeh MOT diagram mai sigma 2pz niche ana chaiye na kyun ki total e is greater tha 14.......

[@chemlogs]

@@maheshbs-p-0176 this is an experimentally determined diagram also its a hetero unclear diatomic molecule so we can't use general rule here

[@Inksgraph098]

Nice

[@arijitsinghsskill7279]

Osm