That's how a coworker landed himself in the hospital. We were clearing out some old bottles from a seldomky used workshop and came across a large brown glass bottle. Instead of carefully smelling the cap, he proceeded to forcefully inhale with his nose right up to the bottle: it contained ammonia.
@@MicraHakkinen My colleague once wanted to flush ammonia solution from a burette after a titration with is breath. Well... One has to breath in before one can breath out and he inhaled with the burette already at his lips. Thankfully it had no effect on his health. Don't blow into burettes, wait just a little for the reagent to trickle out itself.
@@Kycilak This only slightly related, but you made me remember an event from my long past. I was a little kid getting his tonsils out and they were using ether as the anesthetic. I told you it was a long time ago. I was struggling with the mask so the anesthesiologist said, “Don’t you like that smell? Just blow it away as hard as you can.” I did. What is the next thing you do after you have blown all the air out of your lungs? Right.
Ytterbium has a special place in my heart - I did a report on it in high school (20+ years ago), because it was the 'most random' element I could think of. I had no idea it could be so lively!
You're like a Carl Sagan of Chemistry. You seem so down to earth, but your excitement for chemistry and the way you present your exploration makes me excited to learn about chemistry, and explore it with you.
he is just 75 years old. That's not close to end of life in the UK. It's 80 years for men, 84 for women, but it's an average. Ther is a death peak however at age 87.
Whats great about ytterbium is its gaining use in semiconductor arena. Its also being used to replace other,very toxic substances,while its self,is very low in toxicity.
What a delightful surprise! First thing this morning a new Periodic video! I've been binge watching the periodic videos and just passed Ytterbium the day before. Thank you Professor, Neil and Brady for a lovely start to the day.
Ytterbium has a quasi-stable +2 oxidation state that can persist in water in the presence of a strong reducing agent like ytterbium metal. The Yb(II) ion is light green in aqueous solution. I think that is why the solution was light green when you were showing the metal dissolving in hydrochloric acid. The Yb(III) was being reduced by the Yb(s) to form Yb(II).
With the right acid, you can make it persist for longer (I've found sulfamic acid does a decent job at stabilizing Yb(II) ions for long periods of time)
It's interesting, the "-by" suffix seems to have crossed the North Sea (possibly with the Vikings?) and appears in the names of British places too: Derby, Grimsby, Whitby, Rugby etc. In fact two of those four are towns on the east coast of Britain, which makes the Viking theory even more plausible.
There is an Utterby in Lincolnshire, though the Oxford Dictionary of Place-names explains it as "Utterby Lincs. Uthterby 1150-60. Probably ‘farmstead or village of a man called Ūhtrēd or Ūhthere’." They do have: Idrigill Highland. (Skye). ‘Outer gully’. OScand. ytri + gil. But they think the ytri in Itteringham Norfolk was a person. Utrincham 1086 (db). Probably ‘homestead of the family or followers of a man called *Ytra or *Ytri’. OE pers. name + -inga- + hām.
In my experience with colour from combustion, heat can destroy the ions needed to get strong colour. We'd often mix in a buffer to try and reduce the reaction temp to extract more colour. Perhaps the PTFE does the same - the PTFE burns first in the flame and provides a cooling effect to preserve the ions responsible for the colour?
The professor is a national treasure. A WORLD treasure even. A treasure of humanity. I don't know if he has one of those educational knighthood medals from the Queen but he really deserves one ❤
I don't know if PTFE is used in fireworks but I do know it is used in certain types of anti-missile decoy flares for military aircraft, as when combined with a metal powder such as magnesium it generates a lot of infrared.
Many metals need a halogen donor to really bring out the flame color; in pyrotechnics, chlorine is usually used, though fluorine can also be found in some compositions. The exact compounds that form or the mechanism by which they enhance the color is to my knowledge little understood. It may be due to "forbidden" molecules that can only exist temporarily within the extreme conditions of the flame due to excitation or ionization. Maybe you guys could make a video about it.
I assumed the halogens just made the element more volatile by forming halides, so more entered the flame to get excited. The lumps of metal mostly combust with such a bright spark that they drown out the colour of the few ions that escape into the flame. Flame tests usually use ionic compounds of the metals rather than the elemental metals.
Its sad that people my age.. my peers see this, and feel bored.. i personally would give my toe to study chemistry in this way.. i find it incredible that you provide this knowledge to youtube.. Godspeed
Very nice experiments! I especially like Yb+PTFE green sparks, ytterbium chromate and unstable yellow Yb2+, which is formed during dissolving ytterbium in HCl (but it is quickly oxidized by oxygen and water to colourless Yb3+).
its always amazing to me when you hear about chemist in history before all the modern microscopes and testing methods , accurately guessing the atomic mass size etc etc. and being only off by a few numbers, shows how talented and smart they really were
Erbium, Terbium, Yttrium, Ytterbium and if I'm not mistaken, Scandium (?), maybe also Holmium (even bigger ?), were all found in this mine. Quite cool but of course the isolation of them and their discoveries go out to the amazing chemists from all over the world who put in the hours.
Dear Sir I rank you as one of the worlds greatest educators. It’s a toss up for first place between you and Johnny ball but you’ve got the ‘fro dude😂 Big love
I recently did a school project where I studied the elements that were discovered in Ytterby, or at least could trace their discovery back to the mine there and this was one of the elements I did.
I once rolled ytterbium into foil, and once alloyed ytterbium with bismuth. It's a very easy metal to shape and form, doesn't corrode as fast as other lanthanides too. I like ytterbium
Your point at 11:06 really resonated with me on a profound level, Professor. 😔 *"The true mark of a Scientist is having no allegiances to any one nation or doctrine, but to the earth and all the lifeforms on it. This is a Scientist - to me"* _Jacque Fresco, 1916-2017, Founder of the proposed Global Systems Approach, The Venus Project, Resource-Based Economy_
I studied Ytterbium (among other elements/isotopes) during my master's degree (a degree called Cand. Scient. in Norway at the time). Not as a chemist, but as a nuclear physicist. (I have no knowledge about the chemical properties of this element). The nuclei of these rare earth elements have fairly evenly spaced energy levels. This means that the energy shells are not very pronounced, and by targeting the nuclei with light isotopes like 3He and 4He nuclei, one can excite the Yb nuclei and "heat" them up. It turns out that you get some sort of phase transitions in the nuclei. Since there are only 170-something particles in Yb, talking about temperatures may not be entirely correct (strictly speaking, you need infinitely many particles to have a temperature, but any macroscopic object will suffice). Apart from that, the temperatures (or "temperature-like" parameter if you like) in question are several billion degrees (if my memory is correct; this was back in the late 90s).
Everytime I see a video in this series, I enjoy Martyn and Neil faffing about in their lab, talking about “a very nice cloudy white precipitate.” Makes me feel like a 13 year-old in high school chemistry class again.
From flambéing pancakes with powdered sugar, in my experience it's most spectacular if you use fine powder and a tea sieve above the flame to prevent lumping. I thing instead of a file, a whetstone would yield finer filings. Or should we call these filings "stonings"? 🤔
Very Nice video, but I think that an awsome property of Ytterbium ions that is the capability of doing photon upconversion should be addressed, since it is a hot topic on the research of rare earth-based materials
Working with Yb as a physicist my own, the green looked similar, but not the same, as the wavelength of 556 nm, corresponding to the 1S0 -> 3P1 transition. TBH, I would have guessed to see a blueish/uv tint at 399 nm coming from the 1S0 -> 1P1 transition (the strongest one on the groundstate).
Professor, your haircut is great. I wish to have so much knowledge in my head, to turn the hair; I still have, white colour like this. Ytterbium was also interesting.
You guys get the greatest element samples! Ah yes, PTFE pyrotechnics are used in various military formulations... But mischmetal filings work fine too...
i'm curious as to how such things would react in pitch the luminescence of crystaline interaction at specific energy levels i'm curious as to if this element has a pressure reaction say if you hit a small bit with a hammer if it would or a large bit with a punch tool in combo with a hammer blow if it has discernible triboluminescence that is detectable without much hastle. great video!
Hi Professor, Ib think many people are waiting desperately for your team to post new videos, also we're missing the other chemistry. Please make an update soon!
Are there any recent toxicology studies in humans for Ytterbium? I gave up looking 20 years ago. I don't know how it is in other countries but the internet in the U.S. acts like it's been lobotomized. My focus is on the triflouride in dentistry used for a radio-opaquing agent. Thanks.
Great video! I was wondering if ytterbium forms any interesting amalgams with mercury or alkaline metals? Also, how would it react to chlorosulfonic acid? Thanks!
Professor; Couldn't you get a similar colour display (not the flashes) by doing a flame loop test on a sample of Ytterbium oxide or Ytterbium Chloride, or another metal salt? Just wondering.
Neil sniffing the ammonium hydroxide to check if it’s still alright to use is the most Neil thing to do 🤣🤣🤣
That's how a coworker landed himself in the hospital. We were clearing out some old bottles from a seldomky used workshop and came across a large brown glass bottle. Instead of carefully smelling the cap, he proceeded to forcefully inhale with his nose right up to the bottle: it contained ammonia.
@@MicraHakkinen My colleague once wanted to flush ammonia solution from a burette after a titration with is breath. Well... One has to breath in before one can breath out and he inhaled with the burette already at his lips. Thankfully it had no effect on his health.
Don't blow into burettes, wait just a little for the reagent to trickle out itself.
@@Kycilak This only slightly related, but you made me remember an event from my long past. I was a little kid getting his tonsils out and they were using ether as the anesthetic. I told you it was a long time ago. I was struggling with the mask so the anesthesiologist said, “Don’t you like that smell? Just blow it away as hard as you can.” I did. What is the next thing you do after you have blown all the air out of your lungs? Right.
As a fellow Neil, I can confirm I would do the same.
That Hauksbee Medal didn't earn itself
I'm so grateful these videos will be accessible to all future generations. Truly a service for humanity
If you solve this problem you can be a billionaire 👉The Connections (2021) [short documentary]💖
Ytterbium has a special place in my heart - I did a report on it in high school (20+ years ago), because it was the 'most random' element I could think of. I had no idea it could be so lively!
I study ytterbium for my PhD! It’s a great element and quite important in quantum computing
Link us to your thesis when you publish? :D
@Memes shorts you can't be an expert on everything, mate. i'd be out of a job for one... ;-)
an ion a day keeps the doctor away!
Wait I'm curious! Could you share more??
amazing! :D
I could listen to the Professor talk for hours. Every video is a blessing!
If you solve this problem you can be a billionaire 👉The Connections (2021) [short documentary]💖
You're like a Carl Sagan of Chemistry. You seem so down to earth, but your excitement for chemistry and the way you present your exploration makes me excited to learn about chemistry, and explore it with you.
If you solve this problem you can be a billionaire 👉The Connections (2021) [short documentary]💖
I'm SO grateful to see Sir Martyn looks healthy and still going strong. He is a treasure and I hope for him to enjoy many, many more years.
he is just 75 years old.
That's not close to end of life in the UK.
It's 80 years for men, 84 for women, but it's an average. Ther is a death peak however at age 87.
Whats great about ytterbium is its gaining use in semiconductor arena. Its also being used to replace other,very toxic substances,while its self,is very low in toxicity.
If you solve this problem you can be a billionaire 👉The Connections (2021) [short documentary]💖
@@VeganSemihCyprus33 🖕
What a delightful surprise! First thing this morning a new Periodic video! I've been binge watching the periodic videos and just passed Ytterbium the day before. Thank you Professor, Neil and Brady for a lovely start to the day.
you folks are continuing to have fun while providing education for the rest of us. thanks y'all!
Ytterbium has a quasi-stable +2 oxidation state that can persist in water in the presence of a strong reducing agent like ytterbium metal. The Yb(II) ion is light green in aqueous solution. I think that is why the solution was light green when you were showing the metal dissolving in hydrochloric acid. The Yb(III) was being reduced by the Yb(s) to form Yb(II).
With the right acid, you can make it persist for longer (I've found sulfamic acid does a decent job at stabilizing Yb(II) ions for long periods of time)
Ytterby can be translated to Outer Village. "Ytter" = Outer. "By" = Village
So the element is really Outervillageium!
It's interesting, the "-by" suffix seems to have crossed the North Sea (possibly with the Vikings?) and appears in the names of British places too: Derby, Grimsby, Whitby, Rugby etc.
In fact two of those four are towns on the east coast of Britain, which makes the Viking theory even more plausible.
@@alexpotts6520 I'm not sure why you describe it as a theory -- it's a well-established fact.
There is an Utterby in Lincolnshire, though the Oxford Dictionary of Place-names explains it as "Utterby Lincs. Uthterby 1150-60. Probably ‘farmstead or village of a man called Ūhtrēd or Ūhthere’."
They do have:
Idrigill Highland.
(Skye). ‘Outer gully’. OScand. ytri + gil.
But they think the ytri in Itteringham Norfolk was a person.
Utrincham 1086 (db). Probably ‘homestead of the family or followers of a man called *Ytra or *Ytri’. OE pers. name + -inga- + hām.
outervillagium, and the other elements outrium, villagium, and lagium (which is basically how ytterbium, yttrium, terbium, and erbium are named lol)
Whatever I’m watching, I immediately drop it to watch these videos when one is released. Thanks Grady, and thanks Professor!!! ☮️ & ❤ from 🇨🇦
In my experience with colour from combustion, heat can destroy the ions needed to get strong colour. We'd often mix in a buffer to try and reduce the reaction temp to extract more colour. Perhaps the PTFE does the same - the PTFE burns first in the flame and provides a cooling effect to preserve the ions responsible for the colour?
The professor is a national treasure. A WORLD treasure even. A treasure of humanity. I don't know if he has one of those educational knighthood medals from the Queen but he really deserves one ❤
He does have that knighthood, he did a video on it. ;)
He does
Merci au professeur et son équipe!
J’ai bien aimé l’entendre parler français.
Longue vie à lui.
Moi aussi et je le trouve très sympathique ! et toujours la cravate avec le tableau périodique !,
Great to see the Professor again. Thanks, Brady. Your channels are veritable gems!
You guys are somehow still pumping out these videos after a solid 10+ years, and remaking them! Pretty cool.
Yeah. Totally agree.
One of the best professors I know of! I would like to study chemistry in Nottingham under his supervision.
I'm always super chuffed when a new video pops up!
I don't know if PTFE is used in fireworks but I do know it is used in certain types of anti-missile decoy flares for military aircraft, as when combined with a metal powder such as magnesium it generates a lot of infrared.
Many metals need a halogen donor to really bring out the flame color; in pyrotechnics, chlorine is usually used, though fluorine can also be found in some compositions. The exact compounds that form or the mechanism by which they enhance the color is to my knowledge little understood. It may be due to "forbidden" molecules that can only exist temporarily within the extreme conditions of the flame due to excitation or ionization. Maybe you guys could make a video about it.
I assumed the halogens just made the element more volatile by forming halides, so more entered the flame to get excited. The lumps of metal mostly combust with such a bright spark that they drown out the colour of the few ions that escape into the flame. Flame tests usually use ionic compounds of the metals rather than the elemental metals.
Its sad that people my age.. my peers see this, and feel bored.. i personally would give my toe to study chemistry in this way.. i find it incredible that you provide this knowledge to youtube.. Godspeed
It is always a pleasure to watch the Periodic videos!
Thank you Professor and team for this video essay on ytterbium.
Greetings,
Anthony
Very nice experiments! I especially like Yb+PTFE green sparks, ytterbium chromate and unstable yellow Yb2+, which is formed during dissolving ytterbium in HCl (but it is quickly oxidized by oxygen and water to colourless Yb3+).
I love it when the Professor and Neil are surprised!
its always amazing to me when you hear about chemist in history before all the modern microscopes and testing methods , accurately guessing the atomic mass size etc etc. and being only off by a few numbers, shows how talented and smart they really were
Erbium, Terbium, Yttrium, Ytterbium and if I'm not mistaken, Scandium (?), maybe also Holmium (even bigger ?), were all found in this mine. Quite cool but of course the isolation of them and their discoveries go out to the amazing chemists from all over the world who put in the hours.
Sir Poliakoff always succeed to make me smile.
In his mouth, every story is wonder
Dear Sir
I rank you as one of the worlds greatest educators.
It’s a toss up for first place between you and Johnny ball but you’ve got the ‘fro dude😂
Big love
Been waiting for a different video. Thanks folks.
I love the professor, cherish him while we can
Thanks for another exciting video. 😊
The music at the end was quite beautiful. ❤
I recently did a school project where I studied the elements that were discovered in Ytterby, or at least could trace their discovery back to the mine there and this was one of the elements I did.
It's so cool y'all still making these videos, really.
Thank you!
Happy day when a new video pops up from THE Professor and his merry band of assistants Thank you for all the hard work filing the metal Neil
I once rolled ytterbium into foil, and once alloyed ytterbium with bismuth. It's a very easy metal to shape and form, doesn't corrode as fast as other lanthanides too. I like ytterbium
Same idea behind ASML UV lithography using tin. 🔥 Great video! 🙌❤️
Your point at 11:06 really resonated with me on a profound level, Professor. 😔
*"The true mark of a Scientist is having no allegiances to any one nation or doctrine, but to the earth and all the lifeforms on it. This is a Scientist - to me"* _Jacque Fresco, 1916-2017, Founder of the proposed Global Systems Approach, The Venus Project, Resource-Based Economy_
I studied Ytterbium (among other elements/isotopes) during my master's degree (a degree called Cand. Scient. in Norway at the time). Not as a chemist, but as a nuclear physicist. (I have no knowledge about the chemical properties of this element).
The nuclei of these rare earth elements have fairly evenly spaced energy levels. This means that the energy shells are not very pronounced, and by targeting the nuclei with light isotopes like 3He and 4He nuclei, one can excite the Yb nuclei and "heat" them up. It turns out that you get some sort of phase transitions in the nuclei. Since there are only 170-something particles in Yb, talking about temperatures may not be entirely correct (strictly speaking, you need infinitely many particles to have a temperature, but any macroscopic object will suffice). Apart from that, the temperatures (or "temperature-like" parameter if you like) in question are several billion degrees (if my memory is correct; this was back in the late 90s).
Neil seems to be a super villain level authority on what to do and not do in the lab. I like him. Maybe tell us more about his background?
It is a great day every time there is a new "Periodic Table of Videos" ;)
Great video! Dr Poliakoff (and Neil, literally) was on 🔥!!
I measured isotope shifts in Ytterbium (and Dysprosium and Erbium) in my professor's lab many years ago.
Hearing a professor say 'Jazz it up' made my day
Hey! I like that Pyraminx you have on the desk (bottom right corner when the camera is on the Professor)
Everytime I see a video in this series, I enjoy Martyn and Neil faffing about in their lab, talking about “a very nice cloudy white precipitate.” Makes me feel like a 13 year-old in high school chemistry class again.
I think the most iconic line from this channel is "I persuaded Neil"
All elements are exciting.
great video, I like the periodic table and the science stuff behind it 👍 😊🎉
From flambéing pancakes with powdered sugar, in my experience it's most spectacular if you use fine powder and a tea sieve above the flame to prevent lumping.
I thing instead of a file, a whetstone would yield finer filings. Or should we call these filings "stonings"? 🤔
Rejoice rejoice rejoice! A new Periodic Table of Videos element video!
Wishing great health to our Professor.
Always a pleasant surprise when a new video is released.
"I persuaded Neil..."
- the last think you hear before a large explosion.
Who ever makes a joke about this element deserves an Oscar and a Nobel Prize.
I love watching and hearing Professor Chaos.
Very Nice video, but I think that an awsome property of Ytterbium ions that is the capability of doing photon upconversion should be addressed, since it is a hot topic on the research of rare earth-based materials
Interesting and a lot of fun to watch. Thanks for another great periodic table video.
Working with Yb as a physicist my own, the green looked similar, but not the same, as the wavelength of 556 nm, corresponding to the 1S0 -> 3P1 transition. TBH, I would have guessed to see a blueish/uv tint at 399 nm coming from the 1S0 -> 1P1 transition (the strongest one on the groundstate).
The green transition is right at the sweet spot for your eyes' photoreceptors...the near UV transition, not so much.
Professor, your haircut is great. I wish to have so much knowledge in my head, to turn the hair; I still have, white colour like this. Ytterbium was also interesting.
I have an educational shower curtain. Printed on it is Periodic Table of Elements.
"really nice sparks and colours, and some quite nice salts as well." "Like it." (0:53)
I really admire the detached scientific tone of this series.
7:25 "But a lump of metal isn't very useful."
Suit yourself but I, for one, welcome our new robot overlords.
"There is a single light of science, and to brighten it anywhere is to brighten it everywhere."
loved the anecdote about marignac's science dungeon
You guys get the greatest element samples! Ah yes, PTFE pyrotechnics are used in various military formulations...
But mischmetal filings work fine too...
i'm curious as to how such things would react in pitch the luminescence of crystaline interaction at specific energy levels i'm curious as to if this element has a pressure reaction say if you hit a small bit with a hammer if it would or a large bit with a punch tool in combo with a hammer blow if it has discernible triboluminescence that is detectable without much hastle. great video!
Omg that's wild! The colors are amazing!
I'm still curious how they precisely scaled atomic weights etc. 100-150 years ago.
Thank you for making Chemistry interesting!
Next you try alloying ytterbium with some other metals and measuring their mechanical properties for another video.
Welcome back, you were missed
I spent my summers in Ytterby and I never even knew about this element!
Cody'slab just dropped a video and bow you did crazy
The PTFE reaction was a fun surprise!
Is nobody gonna talk about him rolling his R’s?!? Emerrrrald Green
New element always a great day
I love how these highly educated intellectuals still revert to what “does it look like when we burn it? “
Thank you so much for what you are so amazingly do!
Why, if one is to "labour," does one not do so in a "labouratory?"
I love that periodic table of patrons.. Wierdly sad music, though. Has more of a mourning vibe rather than a warm one.
9:33 This label has me intrigued. Enigma White Edition: Ultimate chain powder.
What is all that about?
Good to see you in health professor!
Been missing you.
There you are...
Hi Professor, Ib think many people are waiting desperately for your team to post new videos, also we're missing the other chemistry. Please make an update soon!
isn't there a better way to deliver a sample of filings/powder into a naked flame for direct inflammation?
Ytterbium is used in fiber laser resonators to generate the laser beam that cuts metals.
Does a flame test with the chloride give a bright green?
When can we see a new video about Tungsten (W) ?
Sp happy to see you back!❤️
Are there any recent toxicology studies in humans for Ytterbium? I gave up looking 20 years ago. I don't know how it is in other countries but the internet in the U.S. acts like it's been lobotomized. My focus is on the triflouride in dentistry used for a radio-opaquing agent. Thanks.
Did Neil speak? When the acid goes in. "Oopsie daisies,,," 8:11
can you guys show us how they get the ts steam diagram. assume you will do it from scratch
Great video! I was wondering if ytterbium forms any interesting amalgams with mercury or alkaline metals? Also, how would it react to chlorosulfonic acid? Thanks!
It would be interesting to know what experimental method was used to determine the atomic wt?
Professor; Couldn't you get a similar colour display (not the flashes) by doing a flame loop test on a sample of Ytterbium oxide or Ytterbium Chloride, or another metal salt? Just wondering.
The sparks look great, but would it be feasible to make a spectral picture/analysis of it ?
Or it that to geeky for the channel?
If I had to guess, the fluorine in the PTFE is acting in a similar way that chlorine donors do in pyrotechnic compositions.
Watching your computer equipment change through the ages has been such a delight. 🥰