Alkene Addition Reactions: Crash Course Organic Chemistry #16
Вставка
- Опубліковано 7 вер 2024
- Like a trendy dance, a fighting combo, or a secret handshake, organic reactions can be broken down into simpler steps. In this episode of Crash Course Organic Chemistry, we’ll specifically be looking at alkene addition reactions, and with each new reaction ask ourselves three questions to help us puzzle through the mechanism and understand what’s going on.
Episode Sources:
Le Couteur, P, Burreson, J. Napoleon’s Buttons: 17 molecules that changed history., Penguin, New York, 2004, Chapter 1.
Whipps, H., “How the Spice Trade Changed the World,” www.livescienc... Last accessed, 3/28/2020.
Henriques, Martha, “How spices changed the ancient world,” www.bbc.com/fut... Last accessed, 3/28/2020.
Hashimoto, K., Yaoi, T., Koshiba, H., Yoshida, T., Maoka, T., Fujiwara, Y., Yaamoto, Y, Mori, K., “Photochemical Isomerization of Piperine, a Pungent Constituent of Pepper”, Food Sci. Technol., Int. 1996, 2 (1), 24-29.
Series Sources:
Brown, W. H., Iverson, B. L., Ansyln, E. V., Foote, C., Organic Chemistry; 8th ed.; Cengage Learning, Boston, 2018.
Bruice, P. Y., Organic Chemistry, 7th ed.; Pearson Education, Inc., United States, 2014.
Clayden, J., Greeves, N., Warren., S., Organic Chemistry, 2nd ed.; Oxford University Press, New York, 2012.
Jones Jr., M.; Fleming, S. A., Organic Chemistry, 5th ed.; W. W. Norton & Company, New York, 2014.
Klein., D., Organic Chemistry; 1st ed.; John Wiley & Sons, United States, 2012.
Louden M., Organic Chemistry; 5th ed.; Roberts and Company Publishers, Colorado, 2009.
McMurry, J., Organic Chemistry, 9th ed.; Cengage Learning, Boston, 2016.
Smith, J. G., Organic chemistry; 6th ed.; McGraw-Hill Education, New York, 2020.
Wade., L. G., Organic Chemistry; 8th ed.; Pearson Education, Inc., United States, 2013.
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I've been in organic chemistry education for years, and this is beautifully presented
So I’ve been following along as a lay person. I see now why ochem is universally despised.
we are doing addition rxns rn in chem!! timing perfection
How old are you?? We did all this in like grade 10! We also did reaction mechanisms in detail! What do you have??
@@gaurisreenidhi and they go over it again in undergrad and even more detail in Graduate level in the states.
I absolutely love the the Salor Mercury (Salor Moon) reference! That just made my day! Please continue to create great content and add more courses, like physics, to your app too. Thanks!
Hydroboration does not mean “adding water using boron”; it refers, unsurprisingly, to adding a hydrogen and a boron. We use the term for additions of HBR2 even when not following up with oxidation, e.g. when preparing boron species for cross-coupling.
Orgo professors can’t teach, so I gotta watch CC to teach myself
its 37 min past the hour and youtube seems to finally be working in Houston, Tx. just an FYI. try a refresh and see if that helps.
Learned more in this free youtube course than the year-long uni course I'll be paying 9 grand for. You're the best Crash Course.
UA-cam is broken :(
So you can only comment :(
@@TheOneAndOnlyAhmed
So basically Twitter but worse :/
Thank you I thought it was only me
its working for me tho
I think I might have to check back my notes about oxymercuration. It is actually passed my learning time but seeing that reaction makes me really curious. I think you could add some additional notes about the reaction if it is not in the video, it could really help a lot. But overall, really glad seeing more people gain an interest in one of the hardest chemistry fields in my opinion. Cheers!
Thank you so much
This is your best organic chemistry video yet
God bless y’all
my history teacher uses u to teach the lesson everyday
What's the opposite of the Dunning Kruger effect? That's how these videos make me feel.
Whilst trying to break down organic reactions for us, it seems as CrashCourse may have broken UA-cam in the process.
Isn't the regioselectivity of hydroboration driven by the electropositive nature of boron versus hydrogen (causing the delta minus hydrogen to end up on the more electrophilic site), rather than the difference in size?
Wish I could watch it
its fine now, for me atleast
Can you please do a crash course about Biophysics.. It would be a great help.
Thank you in advance
1:59 Community reference!!!
Anyone else not able to watch anything on youtube? Literally nothing will play for me.
Yeah, me too :(
Same
oh, i thought it was just my shitty internet acting up again
Same
Thought I broke youtube
Could you please do a review for the MCAT?
Green chemistry practices discourage the use of mercury. We even stopped using mercury thermometers in the laboratory. Is oxymercuration still used today?
I was reading my module about hydrocarbons and this video suddenly pops up on my phone. We click crash course 👊
I've also been trying to practice naming some of the compounds in these videos & I'm uncertain about the name of the pre-reaction alkene at 7:45. Is it (Z)-1-cyclohexyl-2-methylbut-2-ene? I keep google image searching that and (Z)-1-(2-methylbut-2-enyl)cyclohexane and I'm getting some molecules that are very very similar, but no exact matches.
Excellent !!! So much enjoy it. She is wonderfully explaining knowledge.
Sad UA-cams down it looked so cool ;(
Great Community reference with the secret handsake :D Cool cool cool!
We’re just looking back over organic chem right now!
So interesting a very useful and informational UA-cam channel! Thank u guys 🔥🔥🔥
Thanks Crash Course!
Just had my chem exam hahaha this would’ve been helpful
I really really found this helpful. God bless you all richly 🥰
i clear all my doubts from your vdos...thank you didi❤
Ah yes, Ryu, the best of all chemists. M. Bison may be strong, but he doesn’t know JACK about science, despite being able to genetically engineer humans.
Bad time to upload while youtube is down
its finw now, for where i live atleast
omg the troy and abed reference
UA-cam is back!
at 7:45, even without the oxymercuration, would a 1,2-alkyl or 1,2-hydride shift even happen in this reaction? the initial carbocation that forms is *already* a tertiary carbocation. Shifts only occur if they generate a *more stable* carbocation, right? The biggest candidate for a shift seems to be the hydride on the cyclohexane's carbon--but that wouldn't form a more stable carbocation. So it wouldn't even occur in the first place, right? is oxymercuration actually necessary in this particular reaction or am I missing something? I'm really confused because I can't tell if I'm missing something or not.
Thank you for making this btw✨
Craving for your video 🤩
Is youtube down or something i cant watch the videos
Yes it’s down
how am i able to watch it tho?
@@nihaal7750 it was an hour ago
@@dragnstuf good thing I was asleep back then
@@nihaal7750 lol
For benzene halogenation shouldn't we add a catalyst like "Fe"
Benzene shows substitution not addition as benzene would like to keep it's aromaticity very much. If we react it normally with Br in a solvent(like CCl4 or peroxide) it isn't electrophilic enough to get attacked by the benzene C-H bonds so we use a Lewis acid like *FeBr3* which reacts with the bromine and forms a Lewis acid-base complex.
Br-Br + FeBr3 = Br-Br(+)-Fe(-)Br3 [Charges on Br and Fe]
This Lewis acid base complex is sufficiently electrophilic to form a halogenated benzene. (feel free to correct me !)
@@PavanKumar-xv1hg nope you are absolutely correct as far as I know.
I wish my school taught like this❤️
Why it is showing video is unavailable
UA-cam is broken
TROY AND ABED AT 1:55???!!!!
rip youtube
Will there be a inorganic series?🤔🤔
i love you crash course.
when youtube breaks down and you rage because you need this crash course
great content John keep it up
Where's that this voice? I only watch this for that good voice
Love these videos!
UA-cam server down
Since youtube is down the view count has been stuck at 944 for 50 minutes. This means absolutely nothing but I kinda just wanted to point it out.
this is just in time... exam #3 today!
Happy diwali
Vascão sempre presente na história e na ciência! Saudações cruzmaltinas! /+/CRVG/+/
I'm literally having black pepper while watching this
Wish I was in 2nd year Chem rn
1:57 troy and abed in the moooooorning
This video is probably why UA-cam was down.
The people in the comments go:
"HADOKEN!!!"
While learning science.
Teacher: SHORYUKEN!
Ken: Ok. Check out what happens, Ryu, when you add water to an acid rather than an acid to water....
I mean, I’d love to watch it, but...
Tuube of uuu is down
10th!
Another anime refrence---this couldnt get any better the nishinoya-
I LOVE DEM VID
my reddit has been down all day today too, just like yt. Conspiracy emoji
3
Come onnnnn just load MAN
Yay❤️
YT broke
watching this instead of John Wolfe
Rip UA-cam
hello to all the jee aspirants watching this
youtube is down 😭😭😭
Can i just listen to music.
can u add Arabic subtitle ?
Love these videos!!! They are great!! Also check out fundamental raps youtube channel for educational content that are in the form of amazing rap songs!!
unfortunate timing lol
2nd yay
finally a crash course without HANK GREEN
First
I wanted to be first to comment sobs
Where is the video? Dislike
UA-cam is down it’s not CC fault.