E/Z Alkenes, Electrophilic Addition, & Carbocations: Crash Course Organic Chemistry #14

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  • Опубліковано 15 гру 2024

КОМЕНТАРІ • 83

  • @lessgogeezers
    @lessgogeezers 4 роки тому +127

    UA-cam recommended me this 1 day before chemistry exam. Damn, even UA-cam cares more about me than I do.

  • @maglo8
    @maglo8 11 місяців тому +12

    So I’m actually a PhD chemist who mainly does organic chemistry. I watched this in the hope to see if E and Z isomers have different reactivity to HBr. That topic was unfortunately not mentioned….
    But when I listen to this, I’m no longer surprised that so many students tell me that organic chemistry is confusing. If this video here is a good representation on how it’s taught then I would probably also get confused.
    There is no need to introduce a major principle on addition reactions but then spending more time on special cases than on the most common one. And the foundation needs more detail. 1. It’s always like a magnet: negative charge goes towards positive charge to form an intermediate and the reaction takes place if that can easily stabilize into something more favorable. When I start explaining reactions in org chem then I first talk about electronegativity. 2. You need to first explain at length why certain carbocations are more stable than others, practice that a little bit and then apply this to addition reactions. Markovnikov derives from there automatically. Proton shifts can happen occasionally, while methyl shifts are much more rare. If you talk about that then you also need to explain why a methyl group can actually move while most other groups don’t. Better would be not to teach that at all though.

  • @zachheilman784
    @zachheilman784 4 роки тому +58

    I've been following several chemistry channels (NurdRage, NileRed, Explosions&Fire) and this series has really started to connect some of the dots when they talk about the reactions they're doing - thanks so much for these videos!

  • @bleuemoone8710
    @bleuemoone8710 4 роки тому +45

    Could have used this series back when I took ochem but now I'm in biochem so is probably useful still!

  • @anjulovesdoracakes22
    @anjulovesdoracakes22 4 роки тому +17

    First comment!!! I'm currently studying chemistry and didn't understand organic chemistry so well, but after this series, I understood it nicely!

  • @diegoroman7092
    @diegoroman7092 Рік тому +4

    This video was pretty good. Understood some bits and pieces of my lecture today, but this video connected all the dots. Thank you!

  • @masterofalltrades999
    @masterofalltrades999 4 роки тому +103

    Just a day after I took an exam on this...

    • @jneal1347
      @jneal1347 4 роки тому +1

      Same XD

    • @nathatleue
      @nathatleue 4 роки тому +1

      IB HL Chem here! My exam is in 2 weeks lol

  • @vaughnjohnson8767
    @vaughnjohnson8767 4 роки тому +56

    “We can use the Ez method.”
    Me: are you sure about that?

  • @zayrael
    @zayrael 4 роки тому +25

    Absolutely amazing video, the animations help SOOO much and the concepts were explained so well! Made for a great review. Thank you CC for once again carrying my OChem grade.

  • @shelbieht5360
    @shelbieht5360 4 роки тому +116

    Don't even study chemistry I just want to be more aware and knowledgeable

  • @xSuperFryx
    @xSuperFryx 4 роки тому +26

    If you are on a unicycle, your best bet is to practice from a wall. When you fall, the unicycle likes to shoot outward, which could hurt one of your friends.

  • @Thanos-hp1mw
    @Thanos-hp1mw 2 роки тому +1

    This is definitely one of my favorites of crash course.

  • @ShirinRose
    @ShirinRose 4 роки тому +8

    I'm from the Blue Mountains in Australia! So cool to see them featured here 😃

  • @Swuirrell4days
    @Swuirrell4days 4 роки тому +6

    Time to learn

  • @magnesiumswift
    @magnesiumswift 10 місяців тому +1

    9:45 I love this part lol, it's so cool, I'm actually shocked, never been taught in high school

    • @SteveBufz
      @SteveBufz 2 місяці тому

      Hehe what do you know? But isnt high school syllabus mostly fixed?

  • @dianavanwinkle2299
    @dianavanwinkle2299 4 місяці тому

    Honestly the part when she says, "okay, deep breath" is so real.

  • @yahav897
    @yahav897 4 роки тому +13

    Hey, CrashCourse, love the videos. I'm not sure if it's been discussed already, but are there any plans for a mathematics playlist? I'd like to see that.

  • @samudrajs5409
    @samudrajs5409 4 роки тому +3

    This series is really really helpful!
    Seeing Organic Chemistry in a whole different view!

  • @edward_myc
    @edward_myc 2 роки тому +1

    Not "on ze zame zide" 😆 I will remember that for the rest of my life!

  • @ahmedsalafap5898
    @ahmedsalafap5898 4 роки тому +8

    Interesting and useful . Great job on animations of hyperconjugation 👍

    • @SuperAndrewlove
      @SuperAndrewlove 4 роки тому

      Thank you so much! I really racked my brain trying to make the hyperconjugation animation as clear as possible as I thought a lot of the existing references on the concept were kinda hard to understand! I'm glad to hear you found it helpful! :D

    • @Arthur-ks4ho
      @Arthur-ks4ho 2 роки тому

      @@SuperAndrewlove I love your animations. May I ask what program do you use to make them?

    • @SuperAndrewlove
      @SuperAndrewlove 2 роки тому +1

      @@Arthur-ks4ho thanks so much! we use Adobe After Effects for all our Crash Course animations! If you want to see exactly how we do it, there are actually tutorials on the Thought Cafe UA-cam channel!

    • @Arthur-ks4ho
      @Arthur-ks4ho 2 роки тому

      @@SuperAndrewlove thanks bro! ❤️ i would love to animate some reaction mechanics but i tried in adobe animate , what do you think? should i stay in adobe animate or should i switch to after effects?

  • @rambles2727
    @rambles2727 Рік тому +1

    For those confused by later episodes come back to this one and pay attention to markovnikovs rule

  • @JS-vv3mo
    @JS-vv3mo 4 роки тому +3

    woooohoooo......that episode was just more than a series fo me........that was amaazzzzziiiinnnnnnn........😍😍😍😍😍😍😍😍

  • @asmitabhongade4858
    @asmitabhongade4858 4 роки тому +4

    Nice video I love it

  • @mr.scientifictemper3056
    @mr.scientifictemper3056 4 роки тому +4

    great crash course of organic chemistry
    i thank the creators.

  • @Memebrasa.1
    @Memebrasa.1 4 роки тому +3

    Very good

  • @robintoonen8515
    @robintoonen8515 4 роки тому +4

    Love that I am dutch and that there are easier way to memorize german. Entgegen --> tegen(over) ; zuzamen --> samen. Respectively against and together

    • @fukpoeslaw3613
      @fukpoeslaw3613 Рік тому

      Es ist "Zusammen" verdammt noch mal ! Of is 't Nochmal aanmekaar geschreeft?

  • @selmangokdemir7181
    @selmangokdemir7181 Рік тому

    In 4:01, why din't you name it as an alkene?

  • @kiranmanoj9250
    @kiranmanoj9250 4 роки тому +1

    Kudus!! Great video
    I really wanted the same video while I was taking my University organic chem exam.

  • @veronikaz2509
    @veronikaz2509 Рік тому

    how do you know the 1,2-shift will happen or happens?

  • @itsarah
    @itsarah 4 роки тому +3

    Hi! I hope everyone has an amazing day!💞
    I make vidz

  • @JoelJimenezMerejo
    @JoelJimenezMerejo 4 роки тому +5

    It’s the way my teacher was JUST teaching this topic today....

  • @victorvicentin900
    @victorvicentin900 4 роки тому +2

    This was amazing!

  • @JS-vv3mo
    @JS-vv3mo 4 роки тому +3

    thanks crash course team fo helping us in here....🙋🙏😇

  • @maxleibrecht7484
    @maxleibrecht7484 10 місяців тому

    Where is the difference to the Wagner Meerwein Shift ?

  • @lewissiekaiqiang7665
    @lewissiekaiqiang7665 4 роки тому +1

    because your explaination is very awesome

  • @NewtonMD
    @NewtonMD 2 роки тому

    At this point, it feels like I am watching a sci-fi movie with many futuristic terms

  • @adriansyahariakusumah7825
    @adriansyahariakusumah7825 2 роки тому

    3:59 is it supposed to be (Z)-4-bromo-3-ethylpent-3-en-1-yne?

    • @ghaithballich5952
      @ghaithballich5952 2 роки тому +1

      there are a triple bond so using the longest chain, which is hexane. However, I'm confused as why is bromo 5 not 6?

    • @adriansyahariakusumah7825
      @adriansyahariakusumah7825 2 роки тому +1

      @@ghaithballich5952 oh i got it, thx. the chain starts from the "yellow no 1" to the "white no 2" (from upper right to the lower left). Bromo located on Carbon no 5 that double bound with Carbon no 4. In this case, Carbon no 4 attached with ethyl group. So that it is 5-Bromo.

  • @dillonmyers965
    @dillonmyers965 4 роки тому +3

    7:13 that Pizzamas shirt of John lol

  • @vrutipatel9539
    @vrutipatel9539 2 роки тому +1

    Thanks ma'am 😇😇😇😇🌸🌸🌸🌸

  • @tmathis9882
    @tmathis9882 25 днів тому

    The way I remember E isomers is that they are enemies, so of course they are on opposite sides.

    • @crashcourse
      @crashcourse  24 дні тому

      Great mnemonic to remember this!

  • @curtpiazza1688
    @curtpiazza1688 2 роки тому

    Excellent!

  • @margaretgodfrey9946
    @margaretgodfrey9946 4 роки тому +1

    This helped me sooo much

  • @vishen7464
    @vishen7464 7 місяців тому

    thank you!!!!

  • @nihilrocks
    @nihilrocks 2 роки тому

    Markovnikov’s rule states that the electrophile attaches to the most stable part of the carbocation which consists the “least hydrogen”. Can someone back me up…

    • @hetaeramancer
      @hetaeramancer 2 роки тому +1

      When a protic acid (HX) is added to an asymmetric alkene, the acidic hydrogen attaches itself to the carbon having a greater number of hydrogen substituents whereas the halide group attaches itself to the carbon atom which has a greater number of alkyl substituents.

  • @the_roopak_lakhera
    @the_roopak_lakhera 4 місяці тому +1

    IIT JEE

  • @lewissiekaiqiang7665
    @lewissiekaiqiang7665 4 роки тому +1

    I hope you can update the next episode quickly

  • @DailyDoseDocumentary
    @DailyDoseDocumentary 4 роки тому +2

    Interesting.

  • @abhi-wi2mj
    @abhi-wi2mj 4 роки тому +1

    Wohoo thanks for this

  • @mybabyalulu
    @mybabyalulu 7 місяців тому

    Where are the dashes and wedges :’))

  • @zachariahayers6273
    @zachariahayers6273 4 роки тому +1

    Simple mechanics and complex Mechanics Theory

  • @user-ut9vt8gq9s
    @user-ut9vt8gq9s 4 роки тому +1

    Excelent!

  • @maxmusterman3371
    @maxmusterman3371 4 роки тому

    Is this CC nomenclature grammar rules?

  • @andreameigs1261
    @andreameigs1261 2 роки тому

    I read that you have to have IDENTICAL groups on each side of the double bond for it to be cis or trans, but that's not what you are showing here.

  • @hibiscus1105
    @hibiscus1105 4 роки тому +5

    I’m early!!! Yayy😍

  • @enamusanovic5808
    @enamusanovic5808 4 роки тому

    WE NEED MATERIALS SCIENCE COURSE

  • @abdulwaseh8043
    @abdulwaseh8043 4 роки тому +2

    ❤️

  • @AvaaJoyy
    @AvaaJoyy Рік тому

    wait you ate this

  • @darkmaninthedark5623
    @darkmaninthedark5623 4 роки тому +1

    With English subtitle please🙏

  • @fernandopineda5503
    @fernandopineda5503 4 роки тому

    Could you do videos on animal science???

  • @kindlez98
    @kindlez98 4 роки тому +2

    Haha, I knew about (Z) for zussamen but for (E) I thought it was Eigen as in unique because they were in a unique place

  • @bvec97
    @bvec97 4 роки тому

    00:07:25 PIZZAMASSSSSSSSSSS

  • @theclashwarrior5148
    @theclashwarrior5148 4 роки тому +1

    I’m early! If only I got a heart

  • @SoupLegion
    @SoupLegion 4 роки тому

    lol thank you!

  • @fchurca
    @fchurca 4 роки тому +1

    First?

  • @vivi.arreola
    @vivi.arreola Рік тому

    You lost me with the shift stuff ! I hate chemistry