I had a hard time following you, but it clicked when I concentrated on what you say. I would like to thank you, and I appreciate all the efforts to make this video. This video is informative and effective. Keep up. A new microphone is needed. :)
thank you for the video! However can you please explain on 33:05 in the z out case, you put electron on the 1 electron in dxy, 1 electron in dxz, 2 electrons in the dyz? because as I understand as a low spin cmpd, I get 2 electrons in the dxz and 2 electrons in the dyz (the 2 lowest orbitals in the energy diagram).
Sir, at 33:09 you were discussing d4 low spin and since in case of low spin, electrons are paired up in the lower energy levels before going to fill the electrons in higher energy levels. So, shouldn't dxz and dyz orbitals be filled up completely before moving ahead to fill the dxy orbitals? Or since all the orbitals in t2g level are degenerate, we have to follow the hund's rule while filling up the electrons?
Yes in case of d4 low spin but t2g orbital is split so dxz, dyz and dxy all are the orbitals of t2g so must be filled wd electrons... Delta O is overall not only t2g.
Sir at 38:57 , when you were discussing unstability of chelating complexes mentioned that [Cu(en)3]2+ will undergo Jahn Teller distortion and this will cause an elongation in the axial bonds. So my question is - how did you know this will undergo Z-out splitting? I mean, we can't predict it. So can we take any of the elongation - axial or equatorial, since both of them will finally make the complex unstable for sure?
Yes definitely, since we can't predict which elongation or compression it will undergo, but this is sure that there will be changes in bond length along axial and equitorial positions, so there will be unstability. But yes you're correct that elongation and compression can't be predicted.
9:20. Don't you think d3 is asymmetry for both HS and LS? Because I think the more unpaired electron will be asymmetric. And in both HS and LS, they have the same number of unpaired electrons.
Thanku so much sir for every lectures ....I hv doubt in video tht d4 low spin complex you discussed for z in or out why do I fill dxy in z out it is low spin so I should be paired I think
Sir jahn tellor distortion vali video me z out me d4 ki filling shi nhi h. Sare electrons dxz or dyz me aane chahiye please watch it again and reply me
Same problem maine face Kiya Hain, d4 hs mein z in aur z out ka dono choice hain, jin mein se Z in favourable hoga..but d4 ls mein bas ek hi choice milta Hain, woh hain Z out..sare 4 electrons dxz aur dyz mein filled honge...
Sir as u mentioned in this video that co +3 ie d6 system with cl shows high spin ....but co + 3 oxidation state shows always low spin......only with flourine it will show low spin.. So that complex is sym and it wont show J T ...if m not wrong
Sir in d4(L.s).. (How to find Zin/zout) The 4es are frst filled in low level I mean pairing tha electron, but u tell 3rd electron will go higher and then the 4th electron put in a low level ,y??? Pls reply sir
Nice video for better understanding. but i have a confusion that... for d4 (L.S) ( Z-out) all the four electrons goes to the d(xz) and d(yz). I think the 4th electron will not go to the d(xy) orbital
Sir, if an octahedral complex having all same ligands undergoes JT distortion, will resultant tetragonal complex would have inversion centre and accounts no dd transition. Plz clarify. Thank you.
In determining strong and weak distortions, how will it occur for d1 and d5(low spin) ??? What will be the answer sir. Will both show low distortion or will there be any change in my statement??
Sir please answer this question. jahn- teller effect is in the field of. (a) Nuclear physics (b) Nuclear chemistry (c) vibronic interaction (d) kinetic theory of gases
Question at 36.06 should have (b) option also as the answer. Term symbol for d5 is S and in case of S the ground term is A1g. If i am wrong please correct me.
Your argument makes sense, Himani. 1 unpaired e- in t2g set has got only one way of occupancy, i.e , the degeneracy here is 1C1. Hence, the ground-state term symbol A1g is a valid option.
Pls add related topic videos link on ur discription box that more comfort for search the topic and pls take class on energetic mode. Otherwise ur class is too good.
Write out mechanism for the inner-sphere electron transfer reaction between [Co(NH3)5SCN]2+ and [Cr(H2O)6] 2+ that produces the pentaaquo-Nthiocyanatochromium(III) cation as one of its products.
You told in this video...if there is unsymmetrically eg orbital...it will be z out case...but here in this book (solutions of net previous year question paper);there is two options..1) three long and two short 2)two long and three short. But in the book ..1 st option is the answer ..Sir I am confused..plz help
![Orgel Diagram - How to use them [Easiest Explanation]](http://i.ytimg.com/vi/XfO6x4_wCfU/mqdefault.jpg)
Just have patience and watch the complete video. You won't be disappointed. Best ever explanation of the Jahn Teller effect concept.😊
U are gem for south indian student
I had a hard time following you, but it clicked when I concentrated on what you say. I would like to thank you, and I appreciate all the efforts to make this video. This video is informative and effective. Keep up. A new microphone is needed. :)
At 32:30 d4(l.s.)configuration will go to z-out
All four electrons will go to dxz and dyz..
Best explanation ever💥 I watched lot of video on this topic but this video is very understanding and more informative for further studies
I'm really excited for the plenty of information I got from this vedio.
Thankyou thankyou thankyou thankyou thankyou thankyou soooo much sir🙏🙏🙏🙏🙏🙏🙏.
You've made my life easier with JT Distortions, thanks for your help. 👌🙏👌
So glad to hear that 💙
Much more than best 🙏🙏
Thank you sir
Sir your lecturers are soo much sorted...n the best please carry on n upload more till gate 2019
thank you for the video!
However can you please explain on 33:05 in the z out case, you put electron on the 1 electron in dxy, 1 electron in dxz, 2 electrons in the dyz? because as I understand as a low spin cmpd, I get 2 electrons in the dxz and 2 electrons in the dyz (the 2 lowest orbitals in the energy diagram).
Same doubt
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Very good explanation sir. Thanks a lot
Sir really u r the best teacher ...
Excellent.... your video solved all my doubts about JTD... Thanks
:)
Thank u sir for putting so much effort..u r a good teacher!
Sir thanks from depth of my heart. I will b highly thankful to you sir.
you're welcome :)
@@AllBoutChemistry your explanation is excellent sir
Sir, at 33:09 you were discussing d4 low spin and since in case of low spin, electrons are paired up in the lower energy levels before going to fill the electrons in higher energy levels. So, shouldn't dxz and dyz orbitals be filled up completely before moving ahead to fill the dxy orbitals? Or since all the orbitals in t2g level are degenerate, we have to follow the hund's rule while filling up the electrons?
Yes in case of d4 low spin but t2g orbital is split so dxz, dyz and dxy all are the orbitals of t2g so must be filled wd electrons... Delta O is overall not only t2g.
Ur concept explanation is superb. Thank you
Sir at 38:57 , when you were discussing unstability of chelating complexes mentioned that [Cu(en)3]2+ will undergo Jahn Teller distortion and this will cause an elongation in the axial bonds. So my question is - how did you know this will undergo Z-out splitting? I mean, we can't predict it. So can we take any of the elongation - axial or equatorial, since both of them will finally make the complex unstable for sure?
Yes definitely, since we can't predict which elongation or compression it will undergo, but this is sure that there will be changes in bond length along axial and equitorial positions, so there will be unstability. But yes you're correct that elongation and compression can't be predicted.
You are amazing sir keep helping sir... Your videoes helping alot sir...
Excellent video nice explanation
Plzzz upload videos daily...atleast more frequently.... Ur videos help me a lot
Best explanation Sir
9:20. Don't you think d3 is asymmetry for both HS and LS? Because I think the more unpaired electron will be asymmetric. And in both HS and LS, they have the same number of unpaired electrons.
Very good talk. A lot of information and ideas. Thank you!!!
very well explained! thankyou !
Lot of information. Just loved the video. Thank you sir🙏
Thank you for your wonderful teaching skill .💐💐💐
Such a pure base💯 Awesome class
Explained very well sir.. Very helpful✌️
Thanku so much sir for every lectures ....I hv doubt in video tht d4 low spin complex you discussed for z in or out why do I fill dxy in z out it is low spin so I should be paired I think
Sir, you find energy of d4 (H. S.) instead of L. S.?
Best explanation ever. All I need was basic explanation thank you so much!
Please Make more and more videos sir...u r great
nice explanation sir ..very much helpful to chemistry learner 🙏
Sir jahn tellor distortion vali video me z out me d4 ki filling shi nhi h. Sare electrons dxz or dyz me aane chahiye please watch it again and reply me
Same problem maine face Kiya Hain, d4 hs mein z in aur z out ka dono choice hain, jin mein se Z in favourable hoga..but d4 ls mein bas ek hi choice milta Hain, woh hain Z out..sare 4 electrons dxz aur dyz mein filled honge...
Thanks sir.......
Agar aise hi serial se lecture milte rhnge to achha hoga
....crack #NET_JRFDEC2018
zaroor... I'll try
When z-in or z-out situation will occur?
way ofexplanation is excellent.
Thank you very much sir... it is very useful.. explanation superb sir
you're welcome :)
Waiting for MOT Sir
thanks for this vedio....it was amazing...sir i love your way of explanations
Very nice explanation, Thank you
Sir as u mentioned in this video that co +3 ie d6 system with cl shows high spin ....but co + 3 oxidation state shows always low spin......only with flourine it will show low spin.. So that complex is sym and it wont show J T ...if m not wrong
good knoledge with best explanation
Nice explanation Sir👌👌👌👌
Your tricks are awesome. It helps me a lot. Sir,can you plz update a video for naming of co ordination complex?
you mean IUPAC naming of complexes?
In d4 low spin..z out configr. Why we have filled electrons in dxy...?? Since it is low spin we would have ended up filling in dyz and dxz only....
Amazing......,sir thank u so much for making this informative video
Sir in d4(L.s).. (How to find Zin/zout) The 4es are frst filled in low level I mean pairing tha electron, but u tell 3rd electron will go higher and then the 4th electron put in a low level ,y??? Pls reply sir
Did you find the reason ?
Nice video for better understanding. but i have a confusion that... for d4 (L.S) ( Z-out) all the four electrons goes to the d(xz) and d(yz). I think the 4th electron will not go to the d(xy) orbital
I have same opinion, I think he made a mistake.
1 also think so
Fabulous video hats off to you
Sir, if an octahedral complex having all same ligands undergoes JT distortion, will resultant tetragonal complex would have inversion centre and accounts no dd transition. Plz clarify. Thank you.
If we have d1 and d5 (low spin) which one is more likely to undergo Jahn-Teller distortion ?
Excellent explanation...thank u sir
In determining strong and weak distortions, how will it occur for d1 and d5(low spin) ???
What will be the answer sir. Will both show low distortion or will there be any change in my statement??
Sir please answer this question. jahn- teller effect is in the field of. (a) Nuclear physics (b) Nuclear chemistry (c) vibronic interaction (d) kinetic theory of gases
👍thnx for yr effort nd hardwork..
you're welcome :)
Sir thankyou very much for this video plz make more such videos on inorganic chemistry
Very good clip indeed helpfull.keep up the good work sir
Perfect explanation.. Ty sir
Sir please tell me where I'll get link related to this topic previous vedio as u said
oh.. what a detailed explanation. thanks sir .
Thank you 😇
Superb sir,sir please do electro chemistry clasess
question- why cannot d3 undergo pairing in the presence of a strong ligand??
Question at 36.06 should have (b) option also as the answer. Term symbol for d5 is S and in case of S the ground term is A1g.
If i am wrong please correct me.
Your argument makes sense, Himani. 1 unpaired e- in t2g set has got only one way of occupancy, i.e , the degeneracy here is 1C1. Hence, the ground-state term symbol A1g is a valid option.
The ground state for low spin d5 is T1g.the A1g is the ground state for high spin d5
but, how d8 low spin will be symmetrical ???...in case of eg they should get paired
Pls add related topic videos link on ur discription box that more comfort for search the topic and pls take class on energetic mode. Otherwise ur class is too good.
ur videos are amazing sir..Pls make the vedios on Pericyclic reactions and problems on entropy concept
Here is link for Pericyclic Reactions
ua-cam.com/video/-TNBVurWszQ/v-deo.html
whether JT distortion can explain disproportionation of other elements which is present in IB group(Group 18) ???
Excellent teaching
Plz explain d4 filling in z out and z in ....why we give one one electron in LS if degeneracy is not there???
You said d2 is z out is that correct when calculated it shows z-in
Write out mechanism for the inner-sphere electron transfer reaction between
[Co(NH3)5SCN]2+ and [Cr(H2O)6]
2+ that produces the pentaaquo-Nthiocyanatochromium(III)
cation as one of its products.
Sir can you please make a video on banana bonding and back bonding?🙏
In the solid cuCl5(-3 charge of the anion) ion has tow types of bonds...will it be z in or z out case?..please reply Sir..
You told in this video...if there is unsymmetrically eg orbital...it will be z out case...but here in this book (solutions of net previous year question paper);there is two options..1) three long and two short
2)two long and three short.
But in the book ..1 st option is the answer ..Sir I am confused..plz help
Y JT not found in tetrahedral case?
Sir Au+3 show john Tellar distortion or not??
Bro ye 10 videos me coordination chemistry completely ho gya.. I mean regarding gate... Plz.. Reply.... Must
sir u said in d6-d9 we cnt predict d zout nd zin but bht d9 shows zout bcz of eg unsymtry how sir????
Nice explanation
Sir how to calculate CFSE for square planar and square pyramidal and Trigonal bipyramidal complexes
Best teacher
Good information sir
10:48 isnt d8 assymetric @high spin🤔
Very good explanation
superb sir....
What is esr spectrum of Copper 2+
Sir please make Vedio on weak field and strong field ligand s.
Alright
Plz sir.. Only then the topic would be completely useful...
d8 high spin symmetry or Asymmetry.... Plzz tell me im little bit confused...
Thank you sir.. i got my answer you explain very well
Sir please , tell me in which book I will get all of this..
Sir which is the perfect book to prepairing for CSIR NET
Thank you so much sir..
U r too good😊
excellent video
thank you :)
Sir please explain umpolung of reactivity
Bro,Plz make one more videos over spinal (normal and reverse)
Excellent video
thank you :)
Thank you sir 😊😊
sir can you please upload the video regarding f-block elements and bio-inorganic chemistry
TQ so much sir🙃
d7 low spin and high spin both show JT bt who shows more