I had a hard time following you, but it clicked when I concentrated on what you say. I would like to thank you, and I appreciate all the efforts to make this video. This video is informative and effective. Keep up. A new microphone is needed. :)
Sir at 38:57 , when you were discussing unstability of chelating complexes mentioned that [Cu(en)3]2+ will undergo Jahn Teller distortion and this will cause an elongation in the axial bonds. So my question is - how did you know this will undergo Z-out splitting? I mean, we can't predict it. So can we take any of the elongation - axial or equatorial, since both of them will finally make the complex unstable for sure?
Yes definitely, since we can't predict which elongation or compression it will undergo, but this is sure that there will be changes in bond length along axial and equitorial positions, so there will be unstability. But yes you're correct that elongation and compression can't be predicted.
Pls add related topic videos link on ur discription box that more comfort for search the topic and pls take class on energetic mode. Otherwise ur class is too good.
thank you for the video! However can you please explain on 33:05 in the z out case, you put electron on the 1 electron in dxy, 1 electron in dxz, 2 electrons in the dyz? because as I understand as a low spin cmpd, I get 2 electrons in the dxz and 2 electrons in the dyz (the 2 lowest orbitals in the energy diagram).
9:20. Don't you think d3 is asymmetry for both HS and LS? Because I think the more unpaired electron will be asymmetric. And in both HS and LS, they have the same number of unpaired electrons.
Thanku so much sir for every lectures ....I hv doubt in video tht d4 low spin complex you discussed for z in or out why do I fill dxy in z out it is low spin so I should be paired I think
Sir jahn tellor distortion vali video me z out me d4 ki filling shi nhi h. Sare electrons dxz or dyz me aane chahiye please watch it again and reply me
Same problem maine face Kiya Hain, d4 hs mein z in aur z out ka dono choice hain, jin mein se Z in favourable hoga..but d4 ls mein bas ek hi choice milta Hain, woh hain Z out..sare 4 electrons dxz aur dyz mein filled honge...
Sir, at 33:09 you were discussing d4 low spin and since in case of low spin, electrons are paired up in the lower energy levels before going to fill the electrons in higher energy levels. So, shouldn't dxz and dyz orbitals be filled up completely before moving ahead to fill the dxy orbitals? Or since all the orbitals in t2g level are degenerate, we have to follow the hund's rule while filling up the electrons?
Yes in case of d4 low spin but t2g orbital is split so dxz, dyz and dxy all are the orbitals of t2g so must be filled wd electrons... Delta O is overall not only t2g.
Nice video for better understanding. but i have a confusion that... for d4 (L.S) ( Z-out) all the four electrons goes to the d(xz) and d(yz). I think the 4th electron will not go to the d(xy) orbital
Sir please answer this question. jahn- teller effect is in the field of. (a) Nuclear physics (b) Nuclear chemistry (c) vibronic interaction (d) kinetic theory of gases
Sir as u mentioned in this video that co +3 ie d6 system with cl shows high spin ....but co + 3 oxidation state shows always low spin......only with flourine it will show low spin.. So that complex is sym and it wont show J T ...if m not wrong
Question at 36.06 should have (b) option also as the answer. Term symbol for d5 is S and in case of S the ground term is A1g. If i am wrong please correct me.
Your argument makes sense, Himani. 1 unpaired e- in t2g set has got only one way of occupancy, i.e , the degeneracy here is 1C1. Hence, the ground-state term symbol A1g is a valid option.
In determining strong and weak distortions, how will it occur for d1 and d5(low spin) ??? What will be the answer sir. Will both show low distortion or will there be any change in my statement??
Sir in d4(L.s).. (How to find Zin/zout) The 4es are frst filled in low level I mean pairing tha electron, but u tell 3rd electron will go higher and then the 4th electron put in a low level ,y??? Pls reply sir
Sir, if an octahedral complex having all same ligands undergoes JT distortion, will resultant tetragonal complex would have inversion centre and accounts no dd transition. Plz clarify. Thank you.
Write out mechanism for the inner-sphere electron transfer reaction between [Co(NH3)5SCN]2+ and [Cr(H2O)6] 2+ that produces the pentaaquo-Nthiocyanatochromium(III) cation as one of its products.
You told in this video...if there is unsymmetrically eg orbital...it will be z out case...but here in this book (solutions of net previous year question paper);there is two options..1) three long and two short 2)two long and three short. But in the book ..1 st option is the answer ..Sir I am confused..plz help
![Orgel Diagram - How to use them [Easiest Explanation]](/img/n.gif)
Just have patience and watch the complete video. You won't be disappointed. Best ever explanation of the Jahn Teller effect concept.😊
U are gem for south indian student
I had a hard time following you, but it clicked when I concentrated on what you say. I would like to thank you, and I appreciate all the efforts to make this video. This video is informative and effective. Keep up. A new microphone is needed. :)
Best explanation ever💥 I watched lot of video on this topic but this video is very understanding and more informative for further studies
You've made my life easier with JT Distortions, thanks for your help. 👌🙏👌
So glad to hear that 💙
At 32:30 d4(l.s.)configuration will go to z-out
All four electrons will go to dxz and dyz..
I'm really excited for the plenty of information I got from this vedio.
Thankyou thankyou thankyou thankyou thankyou thankyou soooo much sir🙏🙏🙏🙏🙏🙏🙏.
Sir your lecturers are soo much sorted...n the best please carry on n upload more till gate 2019
Very good explanation sir. Thanks a lot
Much more than best 🙏🙏
Thank you sir
Sir really u r the best teacher ...
Excellent.... your video solved all my doubts about JTD... Thanks
:)
Excellent video nice explanation
Thank u sir for putting so much effort..u r a good teacher!
Sir thanks from depth of my heart. I will b highly thankful to you sir.
you're welcome :)
@@AllBoutChemistry your explanation is excellent sir
Best explanation Sir
You are amazing sir keep helping sir... Your videoes helping alot sir...
Very good talk. A lot of information and ideas. Thank you!!!
Plzzz upload videos daily...atleast more frequently.... Ur videos help me a lot
very well explained! thankyou !
Ur concept explanation is superb. Thank you
way ofexplanation is excellent.
Thanks sir.......
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zaroor... I'll try
Thank you for your wonderful teaching skill .💐💐💐
Such a pure base💯 Awesome class
Lot of information. Just loved the video. Thank you sir🙏
Explained very well sir.. Very helpful✌️
Please Make more and more videos sir...u r great
Best explanation ever. All I need was basic explanation thank you so much!
Very nice explanation, Thank you
Thank you very much sir... it is very useful.. explanation superb sir
you're welcome :)
Waiting for MOT Sir
Nice explanation Sir👌👌👌👌
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Superb sir,sir please do electro chemistry clasess
Sir at 38:57 , when you were discussing unstability of chelating complexes mentioned that [Cu(en)3]2+ will undergo Jahn Teller distortion and this will cause an elongation in the axial bonds. So my question is - how did you know this will undergo Z-out splitting? I mean, we can't predict it. So can we take any of the elongation - axial or equatorial, since both of them will finally make the complex unstable for sure?
Yes definitely, since we can't predict which elongation or compression it will undergo, but this is sure that there will be changes in bond length along axial and equitorial positions, so there will be unstability. But yes you're correct that elongation and compression can't be predicted.
Excellent teaching
Pls add related topic videos link on ur discription box that more comfort for search the topic and pls take class on energetic mode. Otherwise ur class is too good.
nice explanation sir ..very much helpful to chemistry learner 🙏
Fabulous video hats off to you
Sir thankyou very much for this video plz make more such videos on inorganic chemistry
Your tricks are awesome. It helps me a lot. Sir,can you plz update a video for naming of co ordination complex?
you mean IUPAC naming of complexes?
thank you for the video!
However can you please explain on 33:05 in the z out case, you put electron on the 1 electron in dxy, 1 electron in dxz, 2 electrons in the dyz? because as I understand as a low spin cmpd, I get 2 electrons in the dxz and 2 electrons in the dyz (the 2 lowest orbitals in the energy diagram).
Same doubt
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thanks for this vedio....it was amazing...sir i love your way of explanations
9:20. Don't you think d3 is asymmetry for both HS and LS? Because I think the more unpaired electron will be asymmetric. And in both HS and LS, they have the same number of unpaired electrons.
Excellent explanation...thank u sir
👍thnx for yr effort nd hardwork..
you're welcome :)
Amazing......,sir thank u so much for making this informative video
Thanku so much sir for every lectures ....I hv doubt in video tht d4 low spin complex you discussed for z in or out why do I fill dxy in z out it is low spin so I should be paired I think
Sir jahn tellor distortion vali video me z out me d4 ki filling shi nhi h. Sare electrons dxz or dyz me aane chahiye please watch it again and reply me
Same problem maine face Kiya Hain, d4 hs mein z in aur z out ka dono choice hain, jin mein se Z in favourable hoga..but d4 ls mein bas ek hi choice milta Hain, woh hain Z out..sare 4 electrons dxz aur dyz mein filled honge...
oh.. what a detailed explanation. thanks sir .
Thank you 😇
Sir, at 33:09 you were discussing d4 low spin and since in case of low spin, electrons are paired up in the lower energy levels before going to fill the electrons in higher energy levels. So, shouldn't dxz and dyz orbitals be filled up completely before moving ahead to fill the dxy orbitals? Or since all the orbitals in t2g level are degenerate, we have to follow the hund's rule while filling up the electrons?
Yes in case of d4 low spin but t2g orbital is split so dxz, dyz and dxy all are the orbitals of t2g so must be filled wd electrons... Delta O is overall not only t2g.
Best teacher
Perfect explanation.. Ty sir
Nice video for better understanding. but i have a confusion that... for d4 (L.S) ( Z-out) all the four electrons goes to the d(xz) and d(yz). I think the 4th electron will not go to the d(xy) orbital
I have same opinion, I think he made a mistake.
1 also think so
Sir please tell me where I'll get link related to this topic previous vedio as u said
Very good clip indeed helpfull.keep up the good work sir
Very good explanation
Sir please answer this question. jahn- teller effect is in the field of. (a) Nuclear physics (b) Nuclear chemistry (c) vibronic interaction (d) kinetic theory of gases
Sir, you find energy of d4 (H. S.) instead of L. S.?
Sir can you please make a video on banana bonding and back bonding?🙏
Good information sir
Sir as u mentioned in this video that co +3 ie d6 system with cl shows high spin ....but co + 3 oxidation state shows always low spin......only with flourine it will show low spin.. So that complex is sym and it wont show J T ...if m not wrong
Question at 36.06 should have (b) option also as the answer. Term symbol for d5 is S and in case of S the ground term is A1g.
If i am wrong please correct me.
Your argument makes sense, Himani. 1 unpaired e- in t2g set has got only one way of occupancy, i.e , the degeneracy here is 1C1. Hence, the ground-state term symbol A1g is a valid option.
The ground state for low spin d5 is T1g.the A1g is the ground state for high spin d5
ur videos are amazing sir..Pls make the vedios on Pericyclic reactions and problems on entropy concept
Here is link for Pericyclic Reactions
ua-cam.com/video/-TNBVurWszQ/v-deo.html
Nice explanation
superb sir....
In determining strong and weak distortions, how will it occur for d1 and d5(low spin) ???
What will be the answer sir. Will both show low distortion or will there be any change in my statement??
Thank you so much sir..
When z-in or z-out situation will occur?
Sir in d4(L.s).. (How to find Zin/zout) The 4es are frst filled in low level I mean pairing tha electron, but u tell 3rd electron will go higher and then the 4th electron put in a low level ,y??? Pls reply sir
Did you find the reason ?
Thank you sir 😊😊
please make on vedio of some analytical topics
TQ so much sir🙃
Sir please make Vedio on weak field and strong field ligand s.
Alright
Plz sir.. Only then the topic would be completely useful...
Sir, if an octahedral complex having all same ligands undergoes JT distortion, will resultant tetragonal complex would have inversion centre and accounts no dd transition. Plz clarify. Thank you.
excellent video
thank you :)
Excellent video
thank you :)
Write out mechanism for the inner-sphere electron transfer reaction between
[Co(NH3)5SCN]2+ and [Cr(H2O)6]
2+ that produces the pentaaquo-Nthiocyanatochromium(III)
cation as one of its products.
U r too good😊
If we have d1 and d5 (low spin) which one is more likely to undergo Jahn-Teller distortion ?
Sir please do number your lectures. It becomes difficult to follow them in sequence later.
Sir please make a video on spinel ,normal and inverse case
sir u said in d6-d9 we cnt predict d zout nd zin but bht d9 shows zout bcz of eg unsymtry how sir????
Thankuuuuuuuu so much sir👌👌👌
Thank u sir... Plzz upload video from Organometallics
10:48 isnt d8 assymetric @high spin🤔
Bro,Plz make one more videos over spinal (normal and reverse)
In d4 low spin..z out configr. Why we have filled electrons in dxy...?? Since it is low spin we would have ended up filling in dyz and dxz only....
Bro ye 10 videos me coordination chemistry completely ho gya.. I mean regarding gate... Plz.. Reply.... Must
whether JT distortion can explain disproportionation of other elements which is present in IB group(Group 18) ???
You said d2 is z out is that correct when calculated it shows z-in
Sir Au+3 show john Tellar distortion or not??
Sir please make video on strong and weak field ligands.
Many many Thanks
In the solid cuCl5(-3 charge of the anion) ion has tow types of bonds...will it be z in or z out case?..please reply Sir..
You told in this video...if there is unsymmetrically eg orbital...it will be z out case...but here in this book (solutions of net previous year question paper);there is two options..1) three long and two short
2)two long and three short.
But in the book ..1 st option is the answer ..Sir I am confused..plz help
question- why cannot d3 undergo pairing in the presence of a strong ligand??
Thank u sir.
Plz explain d4 filling in z out and z in ....why we give one one electron in LS if degeneracy is not there???
Thank you ❤❤
good job sir thank you