The attacked of DMSO at Bromonium ion why took place from less substituted side why not from the other side ? Please help me to clear this doubt .. At 9:47
actually that will not attack on less sustituted side, I just wanted to show that bromonium ion will be generated and DMSO will attack on it. And indeed it will attack on more substituted side.....what happens for a SN1 type rxn. I just casualy showd that.
its ok..... i like this work.... see we do our best....but result is not in our hand! so do whatever u like to do...and give ur best....dont think about outcome!
Sir I have one doubt - when you attck the bromonium ion by DMSO then you show that DMSO attck on less substituted end of bromonium ion but I think when thre is positive charge on any 3+ membered ring then any nucleophile prefer to attack at more substituted side....... Plz sie reply
Hello brother.... I want ur help so plz reply me. The question is i want to convert isolated alkene into conjugated alkene so how can i do this?? Tell me the all the reported methods .......i will be really very thankful to u if u help me.... So must reply bro ..... thanks in advance...😊
U can take any Cylic or acyclic isolated Alkene ...... Nd i wanted to convert it into conjugated alkene..... Do u have any idea about it.... Nd plz search any method is reported or not.... If yes so plz give me the detail about it.... I will be very thankful of u .... Here is my wtsp no.8849275529....if u find the method so plz send the info. About it..... So try again thanks in Advance.... Nd thanks for the reply
That means Reaction with NBS / light give Radical reaction and Reaction with Br2 give addition product ? If cyclohexene react with Br2 then we get dibromo cyclohexane ( addition product ) right ?
Yes....If u have large amount of Br2 u will always get addition pdt.... To get allylic bromination u need to control the amount of Br2 ...And that is done by using NBS
The attacked of DMSO at Bromonium ion why took place from less substituted side why not from the other side ? Please help me to clear this doubt .. At 9:47
actually that will not attack on less sustituted side, I just wanted to show that bromonium ion will be generated and DMSO will attack on it.
And indeed it will attack on more substituted side.....what happens for a SN1 type rxn.
I just casualy showd that.
Chemistry lover okay .. Thanks for the explanation .
Very good video sir...
Thank u. Hatts off to ur efforts. Lecture was really Nice.
welcome.
its ok.....
i like this work....
see we do our best....but result is not in our hand!
so do whatever u like to do...and give ur best....dont think about outcome!
Chemistry lover 👍👍 carry on. Good attitude.
Chemistry lover .thats True u deserve more likes than this.
Thank You for the amazing insight into these problems , it is very much appreciated!
At 10:04 min why not DMS elimination occurs, which is common in many DMSO based oxidation reactions.?
I think positively charged S is more susceptible to attack by water molecule.
U did ido lactonisation and in IL d.b must be at gamma delta postion of carbonly grp
I will check
Please kindly request to make 1 video on Baldwin's rule . I've read this but not getting perfectly .
Yes I'm also thinking of making that
Sir I have one doubt - when you attck the bromonium ion by DMSO then you show that DMSO attck on less substituted end of bromonium ion but I think when thre is positive charge on any 3+ membered ring then any nucleophile prefer to attack at more substituted side....... Plz sie reply
Can you please mention the time stamp?
@@Chemistrylover sir its 9:41......
Sir its bromonium ion its 3-membered ring with +ve charge......
Yes you are correct.
@@Chemistrylover thanks sir for your support......
sir plz tell me 13 26 pr 6 mem ring bnni chahiye thi
5 membered ring formation is kinetically more favourable
Hello brother....
I want ur help so plz reply me.
The question is i want to convert isolated alkene into conjugated alkene so how can i do this?? Tell me the all the reported methods .......i will be really very thankful to u if u help me.... So must reply bro ..... thanks in advance...😊
I tried to search all this thing but did not find the any methods... So plz help me....
U have to tell the specific example
U can take any Cylic or acyclic isolated Alkene ...... Nd i wanted to convert it into conjugated alkene..... Do u have any idea about it....
Nd plz search any method is reported or not.... If yes so plz give me the detail about it.... I will be very thankful of u .... Here is my wtsp no.8849275529....if u find the method so plz send the info. About it..... So try again thanks in Advance.... Nd thanks for the reply
That means Reaction with NBS / light give Radical reaction and Reaction with Br2 give addition product ? If cyclohexene react with Br2 then we get dibromo cyclohexane ( addition product ) right ?
Yes....If u have large amount of Br2 u will always get addition pdt....
To get allylic bromination u need to control the amount of Br2 ...And that is done by using NBS
Yes Sir got it..You've cleared my doubts.. thank you so much ☺️
10.02 oh will be attached to the more substituted carbon
Sir which camera u used for recording video ?
Cell phone
Chemistry lover ok sir thanks
kr kya rh@ hai..