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Phosphazenes inorganic compounds |Main Group Chemistry |P-Block Chemistry
Phosphazenes inorganic compounds, Main Group Chemistry , P-Block Chemistry by Shilmani Verma
Phosphazenes are a class of compounds containing alternating phosphorus (P) and nitrogen (N) atoms in their backbone, often with side groups attached to the phosphorus atoms. These compounds exhibit unique chemical properties and have a wide range of applications in fields like polymer science, catalysis, and materials engineering.
Key Features of Phosphazenes:
1. General Structure:
• The simplest phosphazene is a linear chain with the repeating unit , but many phosphazenes form cyclic or polymeric structures.
• Each phosphorus atom typically has two substituents, such as halogens, alkyl, aryl, or alkoxy groups.
2. Types:
• Cyclophosphazenes: Cyclic compounds, e.g., hexachlorocyclotriphosphazene ().
• Linear Phosphazenes: Short chains or oligomers with the formula .
• Polyphosphazenes: High-molecular-weight polymers, e.g., poly(dichlorophosphazene) ().
3. Bonding and Stability:
• The P=N bonds have partial double-bond character due to resonance, contributing to the stability and unique reactivity of phosphazenes.
• Substituents influence thermal and chemical stability.
4. Synthesis:
• Cyclophosphazenes are often prepared by heating ammonium phosphate salts.
• Polyphosphazenes are synthesized by thermal polymerization of cyclic phosphazenes or through condensation reactions.
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Boron Chemistry For BSc | Main Group Chemistry for BSc | P Block Element
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00:00:00 Introduction and syllabus of boron chemistry 00:03:00 Preparation and structure of borans 00:10:00 structure of diborane, chemical property of diborane, physical property of diborane 00:18:10 type of higher boranes closo , super closo, hyper closo, nido, archano, hypo, klado 00:21:20 Structure of higher borans and bonding property 00:25:30 structure of carborans, isolobal analogy 00:42...
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00:00 Introduction and application of STYX code 02:50 Rule for calculation of STYX code 05:00 Examples for calculation of STYX Code 16:00 Structure and bonding of Higher Boranes Your Queries: STYX number For Boranes STYX Code Main Group Chemistry Main Group Chemistry for CSIR NET Main Group Chemistry for GATE Main Group Chemistry for IIT-JAM Borone Chemistry for CSIR-NET Borone Chemistry for GA...
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Переглядів 85Місяць тому
Chemical Properties of Borazine Borazine, often referred to as "inorganic benzene" due to its structural similarity to benzene, exhibits unique chemical properties arising from its alternating boron (B) and nitrogen (N) atoms in a six-membered ring. Here are the key chemical properties of borazine: Aromaticity: Despite its structural similarity to benzene, borazine has less delocalized π-electr...
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Borazine, often referred to as "inorganic benzene," is a chemical compound with the formula B₃N₃H₆. It is a fascinating compound due to its structural similarity to benzene, despite being composed of alternating boron (B) and nitrogen (N) atoms instead of carbon. Structure and Bonding Molecular Geometry: Borazine has a six-membered ring structure, with alternating boron and nitrogen atoms conne...
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Borazine, often referred to as "inorganic benzene," is a chemical compound with the formula B₃N₃H₆. It is a fascinating compound due to its structural similarity to benzene, despite being composed of alternating boron (B) and nitrogen (N) atoms instead of carbon. Structure and Bonding Molecular Geometry: Borazine has a six-membered ring structure, with alternating boron and nitrogen atoms conne...
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