12th Chem | Chapter 12 | L-2 :- Prepration of Aldehyde From Carboxylic Acid Grignard reagent

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..aaj hmne pda hai....... prepration of aldehyde from carboxylic... grignard reagent
कर्बोक्सिलिक अम्ल द्वाराकार्बोक्सिलिक अम्ल के ca लवण
HCOOH.. methenoic acid
उत्प्रेरित अपघटन.... Mno /575k...... कर्बोक्सिलिक अम्ल कि वाश्प को Mno pr प्रवाहित किया जाता है
co2 +h2o +ch3cooH
ch3 or mg ke bech ka bond tutta h
1)नाइट्राइल द्वारा C =-N.............. H -C =-N +ch3 -Mg -Br -------------H -C =-N +ch3 -Mg -Br -------------H -c ch3 =NMgBr
H -C =-N +ch3 -Mg -Br -------------H -c ch3 =NMgBr --------(H /OH) -------HCCh3 =NH +MgOHBr ---------------(H /OH) -----------H -Cch3oH -NH2 ------------ch3coH +NH3
H -C =-N +ch3 -Mg -Br -------------H -c ch3 =NMgBr --------(H /OH) -------HCCh3 =NH +MgOHBr ---------------(H /OH) -----------H -Cch3oH -NH2 ------------ch3coH(aldihaid) +NH3
2....ii) GR +एस्टर... R -2-OR
Ch3cooch3 +Ch3 -Mg -Br ------------ch3 -cch3O MgBr -o -ch3 ------------Mg Br OCh3 +ch3coch3 (कीटोन)
H cooch3 +Ch3 -Mg -I ------------H -cch3O MgI -o -ch3 ------------MgI OCh3 +ch3coH (aldihaid)
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