Converting Corn Cobs to Furfural: Organic Chemistry

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  • Опубліковано 19 чер 2024
  • It's corn! Corn is a staple of our diet and has been for hundreds of years. It is the second most grown crop, loved by many, and most likely, you will eat a corn product today. After the corn kernels are taken off the cob, we are left with a pile of seemingly useless corn cobs, or are they? It may seem impossible, but we can do chemistry with these discarded cobs and get a pretty fascinating compound, furfural from corn cobs.
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    References and uses:
    1. Kuzmina, Natalia. "Renewable Feedstocks and Biocatalysts: Furoin Condensation." In: Organic Synthesis Laboratory Manual, Chapter 22
    2. Corma, A.; Iborra, S.; Velty, A. "Chemical Routes for the Transformation of Biomass into Chemicals." Chemical Reviews, 2007, 107, 2411-2502.
    Chapters:
    00:00 Introduction
    00:39 Reaction
    02:32 Extraction
    03:45 Analysis
    07:27 Clean up
    07:38 Outro
    Thanks for watching!

КОМЕНТАРІ • 20

  • @strade601
    @strade601 27 днів тому +3

    For furfural applications, you could either transform it into THF which is a great solvent to have around if you want to do Grignard reactions, or reduce it into furfuryl alcohol if you're into rocket science.

  • @jimparsons6803
    @jimparsons6803 27 днів тому +2

    Liked the clip. I recall that in Freshman Chemistry, going way, way back, it was explained that it was this chemical reaction that made much of Chicago. Boggle, did not anticipate that one. I had thought that Chicago had prospered because it was a significant port on the Great Lakes. Then, later, someone else, a different Prof, claimed that it was 'white metals' (tin-based metal alloys) that made Chicago, Chicago. The point being, I gathered, that Chemistry can be a real money maker. Heck, I already knew that. And now, so do you.

    • @WheelerScientific
      @WheelerScientific  27 днів тому

      Yeah, chemistry is a very good money maker due to the importance of all the products that can be made. Petroleum products, Fertilizers, pesticides, pharmaceuticals, and so much more. Life would be very different without all those.

  • @davidfetter
    @davidfetter 27 днів тому

    The Claisen adapter is a good tip. Putting the heating mantle and boiling flask on top of a lab jack or similar is also good. This keeps you from needing to figure out how to get the heating mantle out from under it when stuff's popping off.

    • @WheelerScientific
      @WheelerScientific  25 днів тому +1

      Thats true, I always forget about lab jacks. Very useful, too bad they are so expensive. lol

  • @mistercornell4755
    @mistercornell4755 17 днів тому

    i like the korn in the intro

  • @douro20
    @douro20 27 днів тому

    You could also make levoglucosenone this way, using H2SO4 as the catalyst.

  • @ConnorRoss
    @ConnorRoss 26 днів тому

    cool video, shouldn't the title be Organic chemistry: Converting corn cobs to furfural

  • @interstellarsurfer
    @interstellarsurfer 27 днів тому

    3:35 This is why low-cut filters are a thing.

    • @WheelerScientific
      @WheelerScientific  27 днів тому

      I don't think that would fix the problem you are taking about.

    • @interstellarsurfer
      @interstellarsurfer 27 днів тому

      @@WheelerScientific Certainly not the best way, but expedient and somewhat effective. Table bumps are rather jarring when heard over headphones.

  • @SavinjaLabs
    @SavinjaLabs 27 днів тому

    Isn't furfural decently toxic?

  • @douro20
    @douro20 27 днів тому

    I'm guessing you work in a research lab, and that's how you have access to NMR and GC-MS?

  • @interstellarsurfer
    @interstellarsurfer 27 днів тому +1

    Converting corn to cancer. Nice. 👍

  • @henryisnotafraid
    @henryisnotafraid 27 днів тому

    I think you should maybe Google what sweet bread is. You'll see that the description of what you're smelling is very confusing.

    • @WheelerScientific
      @WheelerScientific  27 днів тому +2

      Sweet Bread and Sweetbread are two different things.

  • @petevenuti7355
    @petevenuti7355 27 днів тому +1

    Is it pronounced more like "fear for all" or "fur for all"
    Unless you are a furryphobic, then same thing..

    • @kevinmarrs3372
      @kevinmarrs3372 27 днів тому +2

      Fur fur Al. Exactly how it’s spelled. Suffix is pronounced Al like in the name Albert. It denotes that’s there’s an aldehyde group.
      The suffix -Ol (pronounced: “all”) denotes an alcohol group